B 74 Boltacheva, N. S. Fluoroalkyl-Containing Lithium 1,3-Diketonates in Reactions with Amines and Ammonium Salts [Electronic resource] / N. S. Boltacheva, T. I. Filyakova, V. N. Charushin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2005. - Vol. 41, № 10. - P1452-1457 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Reactions of fluoroalkyl-containing lithium 1,3-diketonates with amines or ammonium salts in glacial acetic acid or methanol at 20°C provide an efficient synthetic route to fluoroalkyl-containing ?-amino-vinyl ketones. Depending on the conditions, reactions of lithium diketonates with 1-aminonaphthalene lead to formation of both ?-aminovinyl ketones and cyclocondensation products, benzo[h]quinolines. The latter can be obtained in one step without isolation of ?-aminovinyl ketones \\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2005, 41 (10), 1452.pdf |