S 17 Saloutina, L. V. Reactions of 2,3-epoxypolyfluoroalkanes with triethylamine [Electronic resource] / L. V. Saloutina, M. I. Kodess, A. Ya. Zapevalov // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1994. - Vol. 43, № 12. - P2057-2061 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The reactions of 2,3-epoxyperfluoro- and 2,3-epoxy--hydropolyfluoroalkanes with excess triethylamine at elevated temperatures yield secondary alcohols, which are the reduction products of intermediate isomeric ketones. Ring-opening occurs preferentially from the side of the less bulky trifluoromethyl group in all compounds except 2,3-epoxy-6-hydroundecafluorohexane \\\\Expert2\\nbo\\Russian Chemical Bulletin\\1994, 43 (13), 2057-2061.pdf |