S 70 Solvent-free reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl)morpholine. unexpected decyanation in addition to classical aza-Diels–Alder reaction / D. S. Kopchuk, A. F. Khasanov, N. V. Chepchugov, I. S. Kovalev, G. V. Zyryanov, V. L. Rusinov, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2017. - Vol. 53, № 1. - P99-102 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl)morpholine under solventfree conditions has been found to follow two pathways: aza-Diels–Alder reaction and unexpected decyanation of the initial nitriles. The scope of the revealed decyanation reaction has been roughly estimated. \\\\Expert2\\NBO\\Russian Journal of Organic Chemistry\\2017 V 53 N 1 P. 99-102.pdf |