Вид документа : Статья из журнала Шифр издания : 54 Автор(ы) : Ratner V. G., Lork E., Pashkevich K. I., Roeschenthaler G.-V. Заглавие : (E)-1,1,1-trifluoro-4-phenyl-but-2-ene-4-one and trimethyl phosphite Место публикации : Journal of Fluorine Chemistry. - 2000. - Vol. 102, № 1-2. - С. 73-77 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The interaction of (E)-1,1,1-trifluoro-4-phenyl-but-2-ene-4-one (1) with trimethyl phosphite affords in a [4 + 1] cycloaddition the 1,2?5-oxaphospholene 2 as a sole product which upon hydrolysis is transformed into the fluoroalkyl containing ?-ketophosphonate 4. When the reaction is carried out in the presence of small mounts of water, in addition to 2 as a main product, the phosphoric acid ester 6 of the enolic dimer of ketone 1 is also formed. The molecular structure of compound 6 (monoclinic P 2(1)/c with a = 2088.60(2), b = 1403.1(3), c = 1613.8(1) pm, ? = 90, ? = 100.97(1), ? = 90°, Z = 8) was determined, indicating two independent molecules with (RR) and (SS) configuration and disordered CF3 groups.???? Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Ratner, V. G.; Ратнер Виталий Георгиевич; Lork, E.; Pashkevich, K. I.; Пашкевич Казимир Иосифович; Roeschenthaler, G.-V. |