Вид документа : Статья из журнала Шифр издания : 54/K 81 Автор(ы) : Krasnov V. P., Koroleva M. A., Rusinov G. L. Заглавие : Nucleophilic substitution of halogen in 4-halo derivatives of glutamic acid 3. High pressure effect on the stereochemical result of the reaction [Electronic resource] Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1996. - Vol. 45, № 3. - С. 543-544 Систем. требования: http://www.springerlink.com/content/l4q073g857048057/fulltext.pdf Примечания : 27.10.2011 г. ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Reactions of diastereomeric dialkyl N-phthaloyl-4-haloglutamates withpara-anisidine were studied at high pressure, and an additional confirmation of the exactS N2 mechanism of the reactions was obtained. Quantitative parameters of the relative reactivity of the diastereomers were found in various solvents, which made it possible to perform the desired synthesis of products of diastereomeric substitution. kg]Key words kw]glutamic acid kw]diastereoselectivity kw]nucleophilic substitution kw]reaction rate constant kw]high pressure. Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Koroleva, M. A.; Rusinov, G. L.