Вид документа :
Шифр издания : 54/C 91
Автор(ы) : Gusev V. Yu., Muksinova D. A., Slepukhin P. A., Radushev A. V.
Заглавие : Crystal structure of copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide
Место публикации : Russian Journal of Coordination Chemistry. - 2012. - Vol.38, №8. - С. 515-518
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): crystal structure --n′,n′-dimethylhydrazide--benzoic acid
Аннотация: X-Ray diffraction analysis was performed for the copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide, Cu(p-(tert-Bu)C6H4CONHNMe2)2 (I). The reagent functions as a bidentate (O,N(2)) ligand giving a five-membered copper-containing ring. The molecule is centrosymmetric. The Cu atom and the metal rings lie in the same plane. The coordination polyhedron of copper is a slightly distorted square. The crystals are monoclinic: a = 16.2634(14) Å, b = 9.0415(8) Å, c = 9.6415(9) Å, α = 90°, β = 100.052(7)°, Z = 2, space group P21/c.

Доп.точки доступа:
Gusev, V. Yu.; Muksinova, D. A.; Slepukhin, P. A.; Radushev , A. V.