Вид документа : Статья из журнала Шифр издания : 54/S 98 Автор(ы) : Ilinykh E. S., Kim D.G., Kodess M. I., Matochkina E. G., Slepukhin P. A. Заглавие : Synthesis of novel fluorine- and iodine-containing [1,2,4]triazolo[3,4-b][1,3]thiazines based 3-(alkenylthio)-5-(trifluoromethyl)-4H-1,2,4-triazole-3-thiols Место публикации : Journal of Fluorine Chemistry. - 2013. - Vol.149. - С. 24-29 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): synthesis--fluorine-containing--iodides Аннотация: In this paper we report the synthesis of novel S-alkenyl derivatives of 5-(trifluoromethyl)-4H-1,2,4-triazole-3-thiol via alkenation reaction with different alkenyl halides. Reaction between the resulting S-alkenation products and iodine proceeds regiospecifically to give new fused fluorine- and iodine-containing [1,2,4]triazolo[3,4-b][1,3]thiazine heterocyclic systems. The structure of synthesized compounds was confirmed by mass spectra, IR, 1H, 13C and 19F NMR spectroscopy including 2D 1H–13C HSQC, 1H–1H COSY, 1H–13C HMBC correlations, elemental analysis and single-crystal X-ray diffraction study. -------------------------------------------------------------------------------- Доп.точки доступа: Ilinykh, E. S.; Kim, D.G.; Kodess, M. I.; Кодесс Михаил Исаакович; Matochkina, E. G.; Slepukhin, P. A.