Вид документа : Статья из журнала Шифр издания : 54/U 62 Автор(ы) : Boltacheva N. S., Slepukhin P. A., Chizhov D. L., Yachevskii D. S., Filyakova V. I., Charushin V. N. Заглавие : Unusual transformations of lithium enolate of ethyl 4,4,4-trifluoro-3-oxobutanoate Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2012. - Vol.61, №3. - С. 563-567 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): lithium--enolates--unusual reactions Аннотация: The present paper describes unusual reactions of lithium enolate of ethyl 4,4,4-trifluoro-3-oxobutanoate with ammonium acetate and 1-aminonaphthalene. These reactions produce 4-amino-2,6-bis(trifluoromethyl)pyridine and 4-trifluoromethyl-2-[(Z)-1,1,1-trifluoroprop-1-en-2-ol-1-yl]benzo[h]quinoline, respectively. The reaction of 1,1,7,7,7-hexafluoroheptane-2,4,6-trione hydrate with 1-naphthylamine gives a mixture of 4-trifluoromethyl-2-[(Z)-1,1,1-trifluoroprop-1-en-2-ol-1-yl]benzo[h]quinoline and N,N′-bis(naphth-1-yl)-2,6-bis(trifluoromethyl)pyridine-4(1H)-imine, respectively Доп.точки доступа: Boltacheva, N. S.; Slepukhin, P. A.; Chizhov, D. L.; Чижов Дмитрий Леонидович; Yachevskii, D. S.; Filyakova, V. I.; Филякова Вера Ивановна; Charushin, V. N.