Вид документа : Статья из журнала Шифр издания : 54/R 30 Автор(ы) : Filyakova T. I., Zapevalov A. Ya., Kodess M. I., Slepukhin P. A., Saloutin V. I. Заглавие : Reactions of perfluoro(2,3-epoxy-2-methylpentane) with o-phenylenediamine and ethylenediamine Место публикации : Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2013. - Vol.49, №3. - С. 350-355 Примечания : Библиогр.: с. 355 (16 ref.) ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): o-phenylenediamine --ethylenediamine--c-n bond Аннотация: Perfluoro(2,3-epoxy-2-methylpentane) reacted with o-phenylenediamine and ethylenediamine via cleavage of the C-C bond to produce 2,2,3,3,3-pentafluoro-N-[2-(2,2,2-trifluoro-1-trifluoromethylethylamino)-phenyl]propanamide and 2,2,3,3,3-pentafluoro-N-[2-(2,2,2-trifluoro-1-trifluoromethylethylamino)ethyl]-propanamide, respectively. Presumably, these compounds are formed as a result of rearrangement of intermediate ketone generated by intramolecular haloform-type reaction. According to the NMR and X-ray diffraction data, 2,2,3,3,3-pentafluoro-N-[2-(2,2,2-trifluoro-1-trifluoromethylethylamino)phenyl]propanamide in crystal exists as Z conformer with respect to the amide C-N bond Доп.точки доступа: Filyakova, T. I.; Филякова Татьяна Ивановна; Zapevalov, A. Ya.; Запевалов Александр Яковлевич; Kodess, M. I.; Кодесс Михаил Исаакович; Slepukhin, P. A.; Saloutin, V. I.