Вид документа : Статья из журнала Шифр издания : 54/S 98 Автор(ы) : Tolshchina S. G., Ishmetova R. I., Ignatenko A. V., Korotina A. V., Slepukhin P. A., Charushin V. N. Заглавие : Synthesis and transformations of cyanomethyl-1,2,4,5-tetrazines Место публикации : Chemistry of Heterocyclic Compounds. - 2013. - Vol.49, №4. - С. 604-617 Примечания : Библиогр.: с. 617 (18 ref.) ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): s-tetrazine --malonodinitrile--nucleophilic substitution Аннотация: Derivatives of s-tetrazine containing malonodinitrile, ethyl cyanoacetate, and 1,3-indanedione fragments were synthesized by the nucleophilic substitution of heterocyclic groups in 3,6-diazolyl-1,2,4,5-tetrazines. Coordination compounds of the cyanomethyltetrazine anion with Cu+, Mn2+, and the tetrathiafulvalene radical cation were obtained, and their structures were determined. A transformation of cyanomethyltetrazines to pyrrolo[1,2-b][1, 2, 4, 5]tetrazines catalyzed by metal cations was discovered Доп.точки доступа: Tolshchina, S. G.; Ishmetova, R. I.; Ишметова Рашида Иршотовна; Ignatenko, A. V.; Korotina, A. V.; Slepukhin, P. A.; Charushin, V. N.