Вид документа : Статья из журнала Шифр издания : 54/O-97 Автор(ы) : Gorbunova T. I., Pervova M. G., Panyukova A. A., Zapevalov A. Ya., Saloutin V. I. Заглавие : Oxidation of highly chlorinated benzenes and biphenyls with potassium persulfate in the presence of perfluorinated radicals [Электронный ресурс] Место публикации : Russian Journal of General Chemistry. - 2013. - Vol. 83, №9. - С. 1678-1686 Систем. требования: http://download.springer.com/static/pdf/588/art%253A10.1134%252FS1070363213090090.pd Примечания : Bibliogr. : p. 1686 (25 ref.). - 11.04.2014 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): 1,2,3,4-tetrachlorobenzene--2,4,5-trichlorobiphenyl--2,5,4′-trichlorobiphenyl Аннотация: The interaction of 1,2,3,4-tetrachlorobenzene, 2,4,5-trichlorobiphenyl, 2,5,4′-trichlorobiphenyl, a mixture of 1,2,3- and 1,2,4-trichlorobenzene, and industrial mixtures of polychlorinated biphenyls with potassium persulfate in the presence of potassium perfluorobutyrate has been investigated. The oxidation of highly chlorinated benzenes and biphenyls proceeds with lower conversion than that of the low-chlorinated compounds. The oxidation of the highly chlorinated aromatic substrates is not selective; the reaction mixture contains products of several competitive reactions: addition and elimination of radical species, disproportionation, isomerization, etc. The structures of the products have been determined by means of gas chromatography with mass spectrometric detection Доп.точки доступа: Gorbunova, T. I.; Горбунова Татьяна Ивановна; Pervova, M. G.; Panyukova, A. A.; Zapevalov, A. Ya.; Запевалов Александр Яковлевич; Saloutin, V. I.