Вид документа : Статья из журнала Шифр издания : 54/S 70 Автор(ы) : Kopchuk D. S., Khasanov A. F., Chepchugov N. V., Kovalev I. S., Zyryanov G. V., Rusinov V. L., Chupakhin O. N. Заглавие : Solvent-free reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl)morpholine. unexpected decyanation in addition to classical aza-Diels–Alder reaction Место публикации : Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2017. - Vol. 53, № 1. - С. 99-102 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl)morpholine under solventfree conditions has been found to follow two pathways: aza-Diels–Alder reaction and unexpected decyanation of the initial nitriles. The scope of the revealed decyanation reaction has been roughly estimated. Доп.точки доступа: Kopchuk, D. S.; Khasanov, A. F.; Chepchugov, N. V.; Kovalev, I. S.; Zyryanov, G. V.; Rusinov, V. L.; Chupakhin, O. N. |