Вид документа : Статья из журнала
Шифр издания : 54/D 62
Автор(ы) : Varaksin M. V., Galliamova L. A., Stepanova O. A., Eltsov O. S., Chupakhin O. N., Charushin V. N.
Заглавие : Direct c[sbnd]c coupling of phthalazine-n-oxide with the carboranyl anion – an original approach to c-modification of carboranes
Место публикации : Journal of Organometallic Chemistry. - 2017. - Vol. 830. - С. 93-99
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): carboranes--c[sbnd]c coupling--phthalazine-n-oxide
Аннотация: An original transition metal-free approach based on the direct C[sbnd]C coupling of phtalazine-N-oxide with the carboranyl anion has been developed. A series of the novel C-modified closo-carboranes such as 1-(2-oxido-3-acyl-3,4-dihydrophtalazinyl-4-yl)-1,2-dicarba-closo-dodecaboranes and 1-(2-formylbenzyl)-1,2-dicarba-closo-dodecaborane have been obtained. The synthesized boron clusters could be of interest as promising building blocks in design of BNCT delivery agents.

Доп.точки доступа:
Varaksin, M. V.; Galliamova, L. A.; Stepanova, O. A.; Eltsov, O. S.; Chupakhin, O. N.; Charushin, V. N.