Вид документа : Статья из журнала Шифр издания : Автор(ы) : Verbitskiy E. V., Dinastiya E. M., Eltsov O. S., Zhilina E. F., Schepochkin A. V., Rusinov G. L., Chupakhin O. N., Charushin V. N. Заглавие : Assembly of annulated 1,3-diazapyrenes by consecutive cross-coupling and cyclodehydrogenation of (het)arene moieties Место публикации : Mendeleev communications. - 2020. - Vol. 30, № 2. - С. 142-144 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Di(het)areno[e,l][1,3]diazapyrene core was constructed by FeCl3-mediated intramolecular oxidative cyclodehydrogenation of 5-[2,6-di(het)arylphenyl]pyrimidine precursors, which in turn were obtained by the Suzuki cross-coupling of 5-(2,6-dibromophenyl)pyrimidine derivative with the corresponding (het)arylboronic acids. Molecular orbital calculations as well as redox and photophysical measurements show that the fused products are promising for organic electronic application. Доп.точки доступа: Verbitskiy, E. V.; Dinastiya, E. M.; Eltsov, O. S.; Zhilina, E. F.; Schepochkin, A. V.; Rusinov, G. L.; Chupakhin, O. N.; Charushin, V. N.