Вид документа : Статья из журнала Шифр издания : Г/E 27 Автор(ы) : Kudyakova Y. S., Onoprienko A. Y., Edilova Y. O., Burgart Y. V., Saloutin V. I., Bazhin D. N. Заглавие : Effect of the nature of a fluorinated substituent on the synthesis of functionalized 1,3-diketones Место публикации : Russian chemical bulletin. - 2021. - Vol. 70, № 4. - С. 745-752 ББК : Г Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The synthesis of alkali metal and copper(II) 1-polyfluoroalkyl-4,4-dimethoxypentane-1,3-dionates is reported. The subsequent treatment of these compounds with oxalic acid or ethylenediaminetetraacetic acid disodium salt affords functionalized 1,3-diketones. The nature of the polyfluoroalkyl substituent was found to affect the conditions of the Claisen condensation and the stability of the acetal group in acidic medium. Доп.точки доступа: Kudyakova, Y. S.; Onoprienko, A. Y.; Edilova, Y. O.; Burgart, Y. V.; Бургарт Янина Валерьевна; Saloutin, V. I.; Bazhin, D. N.