Вид документа : Статья из журнала Шифр издания : Г/H 85 Автор(ы) : Tumashov A. A., Vakarov S. A., Sadretdinova L. S., Chulakov E. N., Levit G. L., Krasnov V. P., Charushin V. N. Заглавие : HPLC separation of 2-aryloxycarboxylic acid enantiomers on chiral stationary phases Место публикации : Russian chemical bulletin. - 2021. - Vol. 70, № 5. - С. 900-907 ББК : Г Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The possibility for separating enantiomers of a number of practically significant 2-aryloxycarboxylic acids was studied by normal- and reversed-phase HPLC on popular chiral stationary phases. The best separation parameters were achieved on the chiral phases with the polysaccharide base Chiralcel OD-H and Chiralpack AD under the normal-phase HPLC conditions. The (S)- and (R)-enantiomers of 2-(1-naphthyloxy)- and 2-(2-iodophenoxy)propionic acids with enantiomeric excess ee 99% were isolated using preparative chiral HPLC. Доп.точки доступа: Tumashov, A. A.; Vakarov, S. A.; Sadretdinova, L. S.; Chulakov, E. N.; Levit, G. L.; Левит Галина Львовна; Krasnov, V. P.; Charushin, V. N. |