Вид документа : Статья из журнала Шифр издания : Автор(ы) : Edilova Y. O., Kudyakova Yu.S., Slepukhin P. A., Burgart Ya. V., Saloutin V. I., Bazhin D. N. Заглавие : Influence of trifluoromethyl groups on the crystal packing of the binuclear copper(ii) complex based on N2O3-pentadentate (hydroxy)bis(СF3-enaminoketone) Место публикации : Russian Journal of Coordination Chemistry. - 2021. - Vol. 47, № 9. - С. 631-637 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): enaminoketones--schiff bases--binuclear copper(ii) bases--x-ray structure analysis Аннотация: The reaction of 1,1,1-trifluoro-4-methoxy-3-penten-2-one (L1) with 1,3-diaminopropan-2-ol affords N,N'-(2-hydroxypropane-1,3-diyl)bis(trifluoroacetylacetimine) (H3L2) in a yield of 82%. In the absence of additional bases, the synthesized N2O3 ligand reacts with copper(II) acetate to give the binuclear complex [Cu2L2(OAc)] (I), the structure of which is determined by X-ray structure analysis (CIF file CCDC no. 2071133). Доп.точки доступа: Edilova, Y. O.; Kudyakova, Yu.S.; Slepukhin, P. A.; Burgart, Ya. V.; Бургарт Янина Валерьевна; Saloutin, V. I.; Bazhin, D. N.