Вид документа : Статья из журнала Шифр издания : Автор(ы) : Solovyova Y. V., Pestov A. V., Puzyrev I. S., Pervova M. G., Kuznetsov V. A., Vlasov I. A., Artemiev G. A. Заглавие : Synthesis of δ-Valerolactone Using Stable Hydrogen Peroxide Derivatives Место публикации : Russian Journal of Organic Chemistry. - 2022. - Vol. 58, № 4. - С. 480-483 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The efficiencies of hydrogen peroxide derivatives in the Baeyer–Villiger oxidation of cyclopen­tanone to δ-valerolactone have been compared. The oxidants used were hydrogen peroxide in acetic, formic, or trifluoroacetic acid, magnesium and sodium monoperoxyphthalates, cumene hydroperoxide, and tert-butyl hydroperoxide. The oxidation was carried out in water, aqueous methanol, and water–ethyl acetate. Sodium and magnesium monoperoxyphthalates turned out to provide high conversion and selectivity under mild conditions. Доп.точки доступа: Solovyova, Y. V.; Pestov, A. V.; Puzyrev, I. S.; Pervova, M. G.; Kuznetsov, V. A.; Vlasov, I. A.; Artemiev, G. A.