Вид документа : Статья из журнала Шифр издания : 53/B 16 Автор(ы) : Baidakov V. G., Protsenko S.P., Kozlova Z. R. Заглавие : Thermal and caloric equations of state for stable and metastable Lennard-Jones fluids. I. Molecular-dynamics simulations Место публикации : Fluid Phase Equilibria. - 2008. - Vol. 263, № 1. - С. 55-63 ББК : 53 Предметные рубрики: ФИЗИКА Ключевые слова (''Своб.индексиров.''): equation of state--computer simulation--lennard-jones fluid--metastable phases--spinodals Аннотация: The method of molecular dynamics has been used to calculate the pressure, internal energy and isochoric heat capacity of the Lennard–Jones fluid for 208 states in the range of temperatures 0.35 kBT 2.0 and densities 0.001 1.2. The array of data obtained, along with stable states, includes homogeneous metastable states (supersaturated vapor, superheated and supercooled liquid). Spinodals of supersaturated vapor and superheated liquid have been approximated. In a stable region the data obtained are compared with the results of previous papers. The behavior of thermodynamic properties of the fluid in the event of homogeneity disturbance and formation of micro-heterogeneous (“two-phase”) states has been considered. Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Protsenko, S.P.; Проценко Сергей Павлович; Kozlova, Z. R.; Байдаков Владимир Георгиевич