T 66 Tkachev, N. C. Surface tension and electric capacity of liquid-vapor near-critical interface of assymmetric electrolytes [Text] / N. C. Tkachev, A. Y. Fishman // Progress in Molten Salt Chemistry: Proceedings from the EUCHEM 2000 Conference on Molten Salts (Denmark, August 20-25, 2000). - 2000. - V. 1. - P533-541. - Bibliogr.: p. 541 (18 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ХИМИЯ -- ЭЛЕКТРОЛИТЫ АСИММЕТРИЧНЫЕ -- АСИММЕТРИЧНЫЕ ЭЛЕКТРОЛИТЫ -- НАТЯЖЕНИЕ ПОВЕРХНОСТНОЕ -- ПОВЕРХНОСТНОЕ НАТЯЖЕНИЕ -- ЕМКОСТЬ ЭЛЕКТРИЧЕСКАЯ -- ЭЛЕКТРИЧЕСКАЯ ЕМКОСТЬ -- ЭЛЕКТРОЛИТЫ ПРИМИТИВНЫЕ -- ПРИМИТИВНЫЕ ЭЛЕКТРОЛИТЫ -- ГРАНИЦЫ Аннотация: Equilibrium conditions for appearing of electrical double layer on the liquid-vapor near-critical interface for an asymmetric electrolyte are analyzed. The effect of the double layer formation lead to specific decreasing of the interfacial width and as a result to the decreasing of surface tension in comparison with the symmetric restricted primitive electrolyte (RPM). The dependencies of the interfacial width, surface tension and electric capacity upon the degree of electrolyte's asymmetry have established. Simple formula of the electric capacity was found which is proportional to the inverse radius of the near-critical density-density correlations |