R 59 Ringuede, A. Assessment of Ni/YSZ anodes prepared by combustion synthesis [Text] / A. Ringuede, D. Bronine, J. R. Frade // Solid State Ionics. - 2002. - V. 146, N 3-4. - P219-224 . - ISSN 0167-2738 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ХИМИЯ -- Ni -- НИКЕЛЬ -- YSZ -- Y -- Zr -- ИТТРИЙ -- ЦИРКОНИЙ -- ZrO2-Y2O3 -- ZrO2 -- Y2O3 -- ДИОКСИД ЦИРКОНИЯ -- ОКСИД ИТТРИЯ Аннотация: Homogeneous mixtures of nanocrystalline powders of (NiO+Ni)/YSZ were obtained by combustion synthesis, and used to prepare Ni/YSZ cermets for symmetrical cermet/YSZ/cermet cells. These cells were prepared by co-pressing, co-firing at 1450 C, and reduction in 10 % H2-90 % N2 at 800 C. The resulting Ni/YSZ cermets are porous and adherent to the electrolyte, and its metallic and ceramic components are uniformly distributed. Impedance spectroscopy was used to characterise these symmetrical cells in atmospheres containing H2 and H2O. The impedance spectra show that the electrode reactions comprise at least two processes with different relaxation frequencies. The low frequency contribution of the polarisation resistance is very dependent on the partial pressures of H2 and H2O. The contribution at higher frequency is mainly dependent on temperature |