N 89 Novoselova, A. Thermodynamic properties of thulium and ytterbium in molten caesium chloride [Текст] / A. Novoselova, V. Smolenski // The Journal of Chemical Thermodynamics . - 2010. - Vol. 42, № 8. - С. 973-977. - Bibliogr. : p. 977 (47 ref.) . - ISSN 0021-9614 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ОКИСЛИТЕЛЬНО-ВОССТАНОВИТЕЛЬНЫЕ ПОТЕНЦИАЛЫ -- ТЕРМОДИНАМИЧЕСКИЕ СВОЙСТВА -- TmCl3 Аннотация: This work presents the results of a study of the Tm3+/Tm2+ and Yb3+/Yb2+ couple redox potentials vs. Cl?/Cl2 reference electrode at the temperature range (973 to 1123) K in molten CsCl by direct potentiometric method. Initial concentrations of TmCl3 and YbCl3 in solvents did not exceed 5.0 mol%. Basic thermodynamic properties of the reactions TmCl2(l) + 1/2 Cl2(g) TmCl3(l) and YbCl2(l) + 1/2 Cl2(g) YbCl3(l) were calculated using the temperature dependencies of apparent standard potentials of the couples and .?? \\\\Cserver\\dist\\НБО\\Cтатьи БД ИВТЭ\\The Journal of Chemical Thermodynamics\\JCT2010 V. 42, N 8. - P.973-977.pdf |