V 18 Valence States of 3d Ions in Lanthanum Manganites–Cobaltites, Determined by X-Ray Spectroscopy / V. R. Galakhov, M. A. Melkozerova, T. I. Chupakhina, G. V. Bazuev, M. Raekers, M. Neumann, S. L. Molodtsov // Bulletin of the Russian Academy of Sciences: Physics. - 2008. - Vol. 72, № 10. - P. 1403-1405 : il. - Bibliogr. : p. 1405 (12 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): МАНГАНИТЫ -- КОБАЛЬТИТЫ -- ЛАНТАН Аннотация: The valence states of manganese and cobalt ions in lanthanum manganites–cobaltites La1−xCaxMn0.5Co0.5O3 have been determined by 2p X-ray absorption and 3s X-ray photoelectron spectroscopies. The nanostructured P1 manganite–cobaltite phase with the concentration x= 0, obtained by the citrate method at a temperature of 700°C, is characterized by a valence state of cobalt ions close to 2+ and a valence state of Mn ions of about 3.5+. The P2 phase at the same calcium concentration, synthesized by the high-temperature solid-phase method at a temperature of 1300°C , is characterized by a manganese valence of 3.5+ and a cobalt valence of about 2.3+. An increase in the dopant concentration leads to an increase in the average valence of 3d ions \\\\Expert2\\nbo\\Bulletin of the Russian Academy of Sciences Physics\\2008, V. 72, N 10, P.1403-1405.pdf |