P 56 Phase Transition of ZrH2.3 / R. N. Pletnev, A. Ya. Kupryazhkin, A. V. Dmitriev, E. V. Zabolotskaya> // Inorganic Materials. - 2002. - Vol. 38, № 7. - P. 665-667 : il. - Bibliogr. : p. 667 (12 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ФАЗОВЫЙ ПЕРЕХОД -- ГИДРИД ЦИРКОНИЯ -- ЯМР -- ЯДЕРНЫЙ МАГНИТНЫЙ РЕЗОНАНС Аннотация: The state of hydrogen in tetragonal e-ZrH2.3 was probed by 1H nuclear magnetic resonance spectroscopy. Both the resonance width and Knight shift were found to exhibit anomalies around 380 K, which were interpreted as evidence for a structural phase transition involving hydrogen ordering Полный текст |