H 99 Hyperfine interactions in type beta NaxV205 / N. A. Zhuravlev, A. V. Dmitriev, A. A. Lakhtin, A. G. Maksimov, V. L. Volkov, R. N. Pletnev // Journal of Structural Chemistry. - 1990. - V. 31, № 6. - P899-903 : il. - Bibliogr. : p. 903 (11 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ОКСИДНЫЕ ВАНАДИЕВЫЕ БРОНЗЫ -- ЯМР Аннотация: In the frequency interval 3.9-20 MHz, we have obtained the 23Na and 51V NMR spectra for single crystals of NaxV205 (x = 0.22; 0.27; 0.33). We have shown that the magnetic properties of the given compounds are sufficiently correctly described in the delocalized electron approximation. On the basis of comparison of the experimental parameters of the electric field gradients and the values of the gradients obtained as a result of calculations of the electronic structure, we have established that the Fermi level is formed by the 3d states of electrons at the V I and V 3 positions Полный текст |