H 65 High-Pressure Defect Phase NdxCu3V4O / N. I. Kadyrova, Yu. G. Zainulin, V. L. Volkov, G. S. Zakharova, A. V. Korolev // Russian Journal of Inorganic Chemistry. - 2009. - Vol. 54, № 12. - P1872-1875 : il. - Bibliogr. : p. 1875 (9 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ПЕРОВСКИТОПОДОБНЫЕ ОКСИДЫ -- ФАЗЫ ВЫСОКОГО ДАВЛЕНИЯ Аннотация: A perovskite-like oxide NdxCu3V4O12(space group Im Z= 2,a= 7.278–7.322Å) with cationic vacancies was prepared for the first time under triaxial compression of p= 6.0–9.0 GPa at 0–1300° C. The compound has a metal-type conductivity, paramagnetic properties, and a phase transition Полный текст |