N 57 Ni(II)-Mediated nitrosation of oximes bearing an alfa-CH2 group [Electronic resource] / A. V. Makarycheva-Mikhailova, P. V. Gushchin, M. N. Kopylovich, I. N. Ganebnuikh, V. N. Charushin, M. P. Haukka, J. L. Armando , V. Yu. Kukushkin // Inorganic Chemistry Communications. - 2006. - Vol. 9, № 8. - P869-871 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Heating of NiCl2 · 6H2O with 10-fold excess of an oxime having an CH2 group (1–4) at 100 °C for 1 day in air leads to the formation of the dioxime/ato complexes [Ni(dioxime/ato)2] (5–8) formed due to a novel type of metal-mediated nitrosation. Compounds 5–8 were characterized by elemental analyses, FAB (5–7) or APCI (8) mass-spectrometry, IR, 1H and 13C{1H} spectroscopies (for 8), and X-ray structural study has been performed for 5 and 8; the corresponding ketones (9–12) were identified by LC–MS. \\\\Expert2\\nbo\\Inorganic Chemistry Communications\\2006, v.9, p.869.pdf |