Вид документа : Статья из журнала Шифр издания : 54/N 52 Автор(ы) : Verbitskiy E. V., Baranova A. A., Lugovik K. I., Khokhlov K. O., Cheprakova E. M., Shafikov M. Z., Rusinov G. L., Chupakhin O. N., Charushin V. N. Заглавие : New 4,5-di(hetero)arylpyrimidines as sensing elements for detection of nitroaromatic explosives in vapor phase Место публикации : Dyes and Pigments. - 2017. - Vol. 137. - С. 360-371 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): fluorescence quenching--nitroaromatic explosives--triphenylamines--carbazoles--pyrimidines Аннотация: A series of D–π–A–π–D type dyes based on pyrimidines, bearing thiophene linkers, have been studied as sensing fluorophores. Fluorescence studies have demonstrated that the emission of all derivatives is sensitive to the presence of 2,4,6-trinitrotoluene (TNT) and other nitroaromatic compounds (NACs), in their acetonitrile solutions. The detection limits of fluorophores to NACs proved to be in the range from 10−4 to 10−6 mol/L. The time-resolved fluorescence measurements and theoretical investigation into the quenching mechanism in the presence of fluorophore has been performed. The two types of sensor prototypes for handheld sniffer «Nitroscan» (Plant «Promautomatika», Ekaterinburg, Russia) on the basis of non-woven dry wipe and spunlace non-woven fabric with various quantities of the most sensitive fluorophore have been fabricated. The reusable, reversible and sensitive response of the designed prototypes to NACs enables one to qualify these compounds as promising fluorescent sensory materials for detection of NACs. Доп.точки доступа: Verbitskiy, E. V.; Baranova, A. A.; Lugovik, K. I.; Khokhlov, K. O.; Cheprakova, E. M.; Shafikov, M. Z.; Rusinov, G. L.; Chupakhin, O. N.; Charushin, V. N.