Вид документа : Статья из журнала Шифр издания : Автор(ы) : Smyshliaeva L. A., Varaksin M. V., Fomina E. I., Medvedeva M. V., Svalova T. S., Kozitsina A. N., Charushin V. N., Chupakhin O. N., Demidov O. P., Borovlev I. V., Mensch C., Mampuys P., Maes B. U. W. Заглавие : 1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties Место публикации : Organometallics. - 2021. - Vol. 40, № 16. - С. 2792-2807 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C–H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features in the regioselectivity and mechanism of the investigated SNH transformations. The novel 1,3,7-triazapyrene-based ortho-carboranes obtained have large potential in the field of molecular electronics as organic luminophores, which are characterized by the aggregation-induced emission and dual-emission effects. Доп.точки доступа: Smyshliaeva, L. A.; Varaksin, M. V.; Fomina, E. I.; Medvedeva, M. V.; Svalova, T. S.; Kozitsina, A. N.; Charushin, V. N.; Chupakhin, O. N.; Demidov, O. P.; Borovlev, I. V.; Mensch, C.; Mampuys, P.; Maes, B. U. W.