Вид документа : Статья из журнала Шифр издания : 54/H 62 Автор(ы) : Galliamova L. A., Varaksin M. V., Chupakhin O. N., Slepukhin P. A., Charushin V. N. Заглавие : Heterocyclic and Open-Chain Carboranes via Transition-Metal-Free C-H Functionalization of Mono- and Diazine-N-oxides [Электронный ресурс] Место публикации : Organometallics. - 2015. - Vol. 34, № 21. - С. 5285-5290 Систем. требования: http://apps.webofknowledge.com/ Примечания : Bibliogr. : p. 5290 (27 ref.). - 18.01.16 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): cyclometalated iridium complexes--neutron-capture therapy--pharmacophores Аннотация: For the first time, the direct C(sp(2))-H functionalization methodology has successfully been applied to cause nucleophilic modification of mono- and diazine-N-oxides with the 1,2-closo-carborane moiety. As a result of these cross-coupling reactions uncatalyzed by transition metals, a series of novel C-modified heterocyclic and open-chain (vinyl acetylene) carboranes have been obtained. Complexes of phenanthrolinyl-substituted omicron-carborane with Cu(II) of various architectures have been synthesized. Доп.точки доступа: Galliamova, L. A.; Varaksin, M. V.; Chupakhin, O. N.; Slepukhin, P. A.; Charushin, V. N.