Вид документа : Статья из журнала Шифр издания : 54/O-72 Автор(ы) : Kovalev I. S., Kopchuk D. S., Zyryanov G. V., Rusinov V. L., Chupakhin O. N., Charushin V. N. Заглавие : Organolithium compounds in the nucleophilic substitution of hydrogen in arenes and hetarenes [Электронный ресурс] Место публикации : Russian Chemical Reviews. - 2015. - Vol. 84, № 12. - С. 1191-1225 Систем. требования: http://iopscience.iop.org/article/10.1070/RCR4462/pdf Примечания : Bibliogr. : p. 1224-1225 (237 ref.). - 19.01.2016 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): nucleophilic substitution--hydrogen--arenes and hetarenes Аннотация: The review considers the most typical examples of the direct non-activated non-catalytic C–C bond formation in arenes and their metal complexes activated by electron-withdrawing substituents in the aromatic nucleus and in hetarenes (azines and their N-oxides, porphyrins, etc.) upon the reactions with aliphatic and (hetero)aromatic (hetero)organolithium nucleophiles. Particular attention is given to the direct introduction of nitroxide radicals and (hetero)organic moieties into mono-, di- and triazines and their N-oxides. The influence of the structures of the (hetero)aromatic substrate and the (hetero)organolithium nucleophile on the reaction pathway and rate and on the structure of the reaction product is analyzed. Доп.точки доступа: Kovalev, I. S.; Kopchuk, D. S.; Zyryanov, G. V.; Rusinov, V. L.; Chupakhin, O. N.; Charushin, V. N.