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1.
Инвентарный номер: нет.
   


   
    1H NMR evidence for 5(4H)-oxazolones formation and racemization [Text] : доклад, тезисы доклада / O. N. Chupakhin, V. P. Krasnov, A. M. Demin, G. L. Levit, M. I. Kodess // XXth European Colloquium on Heterocyclic Chemistry, Stockholm,Sweden, 18-21 Aug. 2002 г. - Stockholm, 2002. - C:2
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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2.
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    2-Arylpropionyl chlorides in kinetic resolution of racemic 3-methyl-2,3-dihydro-4H-[1,4]benzoxazines [Electronic resource] / E. N. Chulakov, D. A. Gruzdev, G. L. Levit, L. Sh. Sadretdinova, V. P. Krasnov, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2011. - Vol.60, №5. - С. 948-954. - Bibliogr. : p. 953-954 (34 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
KINETIC RESOLUTION -- ACYL CHLORIDES -- ENANTIOMERS
Аннотация: Kinetic resolution of racemic 3 methyl 2,3 dihydro 4H [1,4]benzoxazines in the reaction with chiral 2 arylpropionyl chloride predominantly yielded R*,R* diastereomers. Ibuprofen acyl chloride as acylating agent was found to be more selective and sensitive to the changes in the reaction temperature as compared to naproxen acyl chloride and 2 phenylpropionyl chloride

\\\\expert2\\NBO\\Russian Chemical Bulletin\\2011, 60 (5), 948-954.pdf
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3.
Инвентарный номер: нет.
   
   A 10


   
    A comparative study on the acylative kinetic resolution of racemic fluorinated and non-fluorinated 2-methyl-1,2,3,4-tetrahydroquinolines and 3,4-dihydro-3-methyl-2H-[1,4]benzoxazines [Electronic resource] / D. A. Gruzdev, E. N. Chulakov, G. L. Levit, M. A. Ezhikova, M. I. Kodess, V. P. Krasnov // Tetrahedron: Asymmetry . - 2013. - Vol.24, №19. - С. 1240-1246. - Bibliogr. : p. 1246 (21 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
RACEMIC FLUORINATED -- 1,2,3,4-TETRAHYDROQUINOLINES -- BENZOXAZINES
Аннотация: The acylative kinetic resolution of racemic 6-fluoro-2-methyl-1,2,3,4-tetrahydroquinoline, 7,8-difluoro-3,4-dihydro-3-methyl-2H-[1,4]benzoxazine, and their non-fluorinated analogues with (S)-naproxen and N-phthaloyl-(S)-amino acyl chlorides has been carried out. It has been shown that the presence of fluorine atoms in the aromatic fragment of a heterocyclic amine results in the increasing stereoselectivity of acylation with (S)-naproxen acyl chloride and in a decrease in the efficiency of acylative kinetic resolution using N-phthaloyl-(S)-amino acyl chlorides. A method for the preparation of enantiopure (S)-6-fluoro-2-methyl-1,2,3,4-tetrahydroquinoline (ee >99%) was developed

\\\\expert2\\NBO\\Tetrahedron Asymmetry\\2013, in Press, Corr. Proof, 4 Sept.pdf
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4.
Инвентарный номер: нет.
   
   A 18


   
    Acidic hydrolysis of N-acyl-1-substituted 3-amino-1,2-dicarba-closo-dodecaboranes [Electronic resource] / G. L. Levit, A. M. Demin, M. I. Kodess, M. A. Ezhikova, L. Sh. Sadretdinova, V. A. Ol'shevskaya, V. N. Kalinin, V. P. Krasnov, V. N. Charushin // Journal of Organometallic Chemistry. - 2005. - Vol. 690, № 11. - P2783-2786
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Acidic hydrolysis of N-acyl 1-methyl- and 1-phenyl-3-amino-1,2-dicarba-closo-dodecaboranes has been studied. It has been shown that acidic hydrolysis of diastereomeric amides of 1-methyl-3-amino-1,2-dicarba-closo-dodecaborane results in the partial racemization of the target 3-amino-1-methylcarborane. Under the similar conditions, the hydrolysis of N-acyl-3-amino-1-phenyl-1,2-dicarba-closo-dodecaboranes resulted in amide bond cleavage accompanied by simultaneous deboronation with the removal of boron atom at position 6 of carborane cage and formation of 7,8-dicarba-nido-undecaborane derivative according to 11B and 1H NMR spectroscopy.

\\\\Expert2\\nbo\\Journal of Organometallic Chemistry\\2005, v. 690, p.2783.pdf
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5.
Инвентарный номер: нет.
   
   K 81


    Krasnov, V. P.
    Acylactive kinetic resolution of racemic amines using derivatives of chiral acids [Text] : доклад, тезисы доклада / V. P. Krasnov // 15th European Symposium on Organic Chemistry, Dublin, 8-13 July 2007 :abstr. - Dublin, Ireland, 2007. - P38
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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6.
Инвентарный номер: нет.
   
   A 19


   
    Acylactive kinetic resolution of racemic heterocyclic amines using amino acids derivatives [Text] : доклад, тезисы доклада / D. A. Gruzdev, G. L. Levit, E. N. Chulakov, L. Sh. Sadretdinova, T. V. Matveeva, E. A. Il"ichyova, V. P. Krasnov // Fifth International Conference on Organic Chemistry for young Scientists (InterYCOS-2009) "Universities Contribution in the Organic Chemistry Progress", devoted to the 175 th anniversary of D.I.Mendeleevs birthday and 80th anniversary of the Chemistry department of St. Petersburg State University foundation, Saint-Petersburg, 22-25 june 2009 : abstr. - СПб., 2009. - P45 (1-11). - Bibliogr. : p. 46 (9 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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7.
Инвентарный номер: нет.
   
   A 19


   
    Acylative kinetic resolution of racemic amines using N-phthaloyl-(S)-amino acyl chlorides [Text] / D. A. Gruzdev, G. L. Levit, V. P. Krasnov, E. N. Chulakov, L. Sh. Sadretdinova, A. N. Grishakov, M. A. Ezhikova, M. I. Kodess, V. N. Charushin // Tetrahedron: Asymmetry . - 2010. - Vol. 21, № 8. - P936-942
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Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: A comparative study of the kinetic resolution of racemic 2-methyl-1,2,3,4-tetrahydroquinoline and 2,3-dihydro-3-methyl-4H-1,4-benzoxazine using N-phthaloyl-(S)-amino acyl chlorides as chiral acylating agents is described. Temperature and solvent effects on the stereochemical features have been examined. It has been found that N-phthaloyl-(S)-phenylalanyl and N-phthaloyl-(S)-2-phenylglycyl chlorides bearing aromatic substituents close to the stereogenic centre are more stereoselective acylating agents than N-phthaloyl-(S)-alanyl chloride. For the preparative kinetic resolution of racemic amines N-phthaloyl-(S)-phenylalanyl chloride proved to be the most appropriate chiral acylating agent

\\\\Expert2\\nbo\\Tetrahedron Asymmetry\\2010, v. 21, p.936.pdf
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8.
Инвентарный номер: нет.
   
   A 19


   
    Acylative kinetic resolution of racemic amines with N-protected (S)-amino acyl chlorides / D. A. Gruzdev, G. L. Levit, V. P. Krasnov, V. N. Charushin // 18th European Symposium on Organic Chemistry ESOC-2013, Marseille, France, 7-12 July 2013 : book of abstracts. - Marseille (France) , 2013. - 244 (P1-184)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
RACEMIC AMINES -- CHLORIDES -- ACYLATIVE KINETIC RESOLUTION

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9.
Инвентарный номер: нет.
   
   A 19


   
    Acylative kinetic resolution of racemic amines with profens and amino acids derivatives / V. P. Krasnov, G. L. Levit, D. N. Kozhevnikov, M. I. Kodess, D. A. Gruzdev, E. N. Chulakov, V. N. Charushin // International Congress on Organic Chemistry, dedicated to the 150-th anniversary of the Butlerov's Theory of Chemical Structure of Organic Compounds, Kazan, September 18-23, 2001 : book of abstr. - Kazan, 2011. - С. 85
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
KINETIC RESOLUTION -- S-AMINES -- RACEMIC AMINES

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10.
Инвентарный номер: нет.
   
   G 90


    Gruzdev, D. A.
    Acylative kinetic resolution of racemic heterocyclic amines using N-phthaloyl-(S)-amino acyl chlorides with alkyl side chains / D. A. Gruzdev, G. L. Levit, V. P. Krasnov // Tetrahedron: Asymmetry . - 2012. - Vol.23. - С. 1640-1646. - Bibliogr.: p. 1645-1646 (15 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
HETEROCYCLIC AMINES -- RACEMIC AMINES -- ACYL CHLORIDES
Аннотация: A comparative study of the acylative kinetic resolution of racemic 2-methyl-1,2,3,4 tetrahydroquinoline and 3,4-dihydro-3-methyl-2H-[1,4]benzoxazine using N-phthaloyl-(S)-amino acyl chlorides with alkyl side chains has been carried out. The influence of steric factors on the stereoselectivity of the acylation was demonstrated. The (S)-enantiomers of the heterocyclic amines (ee >99%) were obtained in good yields via a kinetic resolution protocol using N-phthaloyl-(S)-leucyl chloride

\\\\expert2\\NBO\\Tetrahedron Asymmetry\\2012, v. 23, p.1640.pdf
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11.
Инвентарный номер: нет.
   
   A 19


   
    Acylative kinetic resolution of racemic heterocyclic amines with (R)-2-phenoxypropionyl chloride / S. A. Vakarov [и др.] // Tetrahedron: Asymmetry . - 2016. - Vol. 27, № 24. - С. 1231-1237. - Bibliogr. : p. 1236-1237 (15 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
HETEROCYCLIC AMINES -- BENZOXAZINES -- 2-METHYLINDOLINE -- KINETIC RESOLUTION
Аннотация: The acylative kinetic resolution of racemic heterocyclic amines such as 3,4-dihydro-3-methyl-2H-[1,4]benzoxazines, 3,4-dihydro-3-methyl-2H-[1,4]benzothiazine, 2-methyl-1,2,3,4-tetrahydro-quinolines and 2-methylindoline with enantiopure (R)-2-phenoxypropionyl chloride has been studied. It has been found that acylation of 3,4-dihydro-3-methyl-2H-[1,4]benzothiazine proceeds with the best stereoselectively when compared with other racemic amines. An efficient method for the preparation of (S)-3,4-dihydro-3-methyl-2H-[1,4]benzothiazine (99.4% ee) via a kinetic resolution protocol was developed. The possibility of recycling (R)-2-phenoxypropionic acid has been demonstrated.

\\\\expert2\\NBO\\Tetrahedron Asymmetry\\2016, v. 27, p.1231.pdf
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12.
Инвентарный номер: нет.
   


   
    Acylative kinetic resolution of racemic methyl-substituted cyclic alkylamines with 2,5-dioxopyrrolidin-1-yl (R)-2-phenoxypropanoate / D. A. Gruzdev, S. A. Vakarov, M. A. Korolyova [et al.] // Organic & biomolecular chemistry. - 2022. - Vol. 20, № 4. - P862-869
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The diastereoselective acylation of a number of racemic methyl-substituted cyclic alkylamines with active esters of 2-phenoxypropanoic acid was studied in detail. The ester of (R)-2-phenoxypropanoic acid and N-hydroxysuccinimide was found to be the most selective agent. The highest stereoselectivity was observed in the kinetic resolution of racemic 2-methylpiperidine in toluene at −40 °C (selectivity factor s = 73) with the predominant formation of (R,R)-amide (93.7% de). To explain the observed stereoselectivity, DFT modelling of the transition states in the reactions of the title acylating agent with 2-methylpiperidine and 2-methylpyrrolidine was performed. The calculated values were in good agreement with experimental data. It has been demonstrated that the acylation proceeds via a concerted mechanism, in which the addition of an amine occurs simultaneously with the elimination of the hydroxysuccinimide fragment. The high stereoselectivity of the (R,R)-amide formation is largely ensured by the lower steric hindrances in the transition states as compared to the formation of (R,S)-amide.

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13.
Инвентарный номер: нет.
   
   L 62


    Levit, G. L.
    Acylative Kinetic Resolution with Chiral Acyl Chlorides as an Efficient Preparative Approach for Enantio Pure Heterocyclic Amines / G. L. Levit, V. P. Krasnov // CHIRALITY 2014 : book of abstr., Prague, Czech Republic, 27-30 July 2014. - 2014. - P. 218 (P-099)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CHIRAL ACYL CHLORIDES -- HETEROCYCLIC AMINES

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14.
Инвентарный номер: нет.
   
   L 62


    Levit, G. L.
    Acylative kinetic resolution with chiral acyl chlorides as an efficient preparative approach for enantio pure heterocyclic amines / G. L. Levit, V. P. Krasnov // CHIRALITY 2014. 26-th International Symposium on Chiral Discrimination, ISCD-26, Prague, Czech Repablic, 27-30 July 2014 : book of asbstracts. - Prague, 2014. - 218 (P-099). - Bibliogr. : p. 218 (2 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
HETEROCYCLIC AMINES -- RESOLVING AGENTS -- SYNTHESIS

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15.
Инвентарный номер: нет.
   
   A 89


   
    Asymmetric Biginelli Reaction Catalyzed by Silicon, Titanium and Aluminum Oxides [Electronic resource] / O. V. Fedorova, Yu. A. Titova, A. Yu. Vigorov, M. S. Toropova, O. A. Alisienok, A. Murashkevich, V. P. Krasnov, G. L. Rusinov, V. N. Charushin // Catalysis Letters. - 2016. - Vol.146, № 2. - С. 493-498
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BIGINELLI REACTION -- PHENYLETHYLAMINE -- ALUMINUM OXIDES
Аннотация: The asym. Biginelli reaction was investigated in the presence of N-​[(2S,​4R)​-​4-​hydroxyprolyl]​-​(S)​-​1-​phenylethylamine as chiral inducer and silicon, titanium or aluminum oxides (individual and mixed, bulk and nanosized) as heterogeneous catalysts. The synthesis of Et (4R)​-​6-​methyl-​2-​oxo-​4-​phenyl-​1,​2,​3,​4-​tetrahydropyrimidine-​5-​carboxylate from benzaldehyde, urea and Et acetoacetate has been described. It has been shown that all studied oxides improve chemo- and stereoselectivity of the Biginelli reaction.

\\\\expert2\\nbo\\Catalysis Letters\\2016, v.146, p.493.pdf
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16.
Инвентарный номер: нет.
   
   B 60


   
    Biotechnological synthesis of new nucleosides based on 2-aminopurine with a bulky 7,8-difluoro-3,4-dihydro-3-methyl-2 h-[1,4]benzoxazine residue at C6 position [Electronic resource] / B. Z. Eletskaya, D. A. Gruzdev, A. Yu. Vigorov, I. D. Konstantinova, G. L. Levit, V. P. Krasnov, V. N. Charushin, A. I. Miroshnikov // FEBS Journal. - 2015. - Vol. 282, № S1 : 40th Congress of the Federation-of-European-Biochemical-Societies (FEBS) - The Biochemical Basis of Life, Berlin, Germany, Jul 04-09 2015. - С. 162
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BIOTECHNOLOGICAL SYNTHESIS -- 2-AMINOPURINE -- NUCLEOSIDES

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17.
Инвентарный номер: нет.
   


   
    Carborane-containing amino acids and peptides: synthesis, properties and applications / D. A. Gruzdev, G. L. Levit, V. P. Krasnov, V. N. Charushin // Coordination Chemistry Reviews. - 2021. - Vol. 433. - Ст. 213753
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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18.
Инвентарный номер: нет.
   
   C 51


   
    Chemoenzymic arabinosylation of 2-aminopurine bearing the chiral fragment of 7,8-difluoro-3-methyl-3,4-dihydro-2H-[1,4]benzoxazines [Electronic resource] / B. Z. Eletskaya, I. D. Konstantinova, A. S. Paramonov, S. E. Esipov, D. A. Gruzdev, A. Yu. Vigorov, G. L. Levit, A. I. Miroshnikov, V. P. Krasnov, V. N. Charushin // Mendeleev Communications. - 2016. - Vol. 26, № 1. - С. 6-8
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PURINE NUCLEOSIDE PHOSPHORYLASE -- 2-AMINOPURINE CONJUGATES
Аннотация: Chemoenzymic transglycosylation of 2-​aminopurine conjugates with enantiomerically pure 7,8-​difluoro-3-​methyl-3,4-dihydro-2H-[1,4]​benzoxazines under the action of recombinant E. coli purine nucleoside phosphorylase afforded the corresponding arabinofuranosides, yields of the target compds. being dependent on both the structure and configuration of the fragment of heterocyclic amine attached at C-​6 position of purine moiety.

\\\\expert2\\nbo\\Mendeleev Communications\\2016, v.26, p. 6-8.pdf
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19.
Инвентарный номер: нет.
   
   C 51


   
    Chemoselectivity in the Reduction of (2S,4S)-4-Amino-5-oxoproline Derivatives with Borane Complexes [Text] / A. Yu. Vigorov, I. A. Nizova, L. Sh. Sadretdinova, M. A. Ezhikova, M. I. Kodess, I. N. Ganebnuikh, V. P. Krasnov // European Journal of Organic Chemistry. - 2011. - № 13. - P2562-2569. - Bibliogr. : p. 2569 (21 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Reduction of the carbonyl groups in N-protected (2S,4S)-4-amino- 5-oxo-1-phenylprolinates with BH(3) complexes resulted in (2S,4S)-4-aminoproline or (2S,4S)-4-aminoprolinol derivatives depending on the reaction conditions and the type of protecting groups used

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20.
Инвентарный номер: нет.
   
   C 74


   
    Complete 11B spectral assignment of 3-amino-1-methyl-1,2-dicarba-closo-dodecarborane [Text] : доклад, тезисы доклада / M. I. Kodess, M. A. Ezhikova, G. L. Levit, V. P. Krasnov, V. A. Ol'shevskaya, V. N. Kalinin, V. N. Charushin, O. N. Chupakhin // Eleventh International Conference on Boron Chemistry "IMEBORON XI", M., July 28-Aug.2, 2002 : abstracts. - M., 2002. - 113 (P-35)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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21.
Инвентарный номер: нет.
   
   D 38


    Demin, A. M.
    Covalent surface modification of Fe3O4 magnetic nanoparticles with alkoxy silanes and amino acids [Электронный ресурс] / A. M. Demin, V. P. Krasnov, V. N. Charushin // Mendeleev Communications. - 2013. - Vol.23, №1. - P14-16
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
Fe3O4 -- MAGNETIC NANOPARTICLES -- ALKOXY SILANES
Аннотация: (3-Aminopropyl)silane-modified magnetic nanoparticles containing ε-aminocaproic acid and l-lysine fragments with free functional groups were obtained by the surface modification of Fe3O4 with alkoxysilane derivatives

\\\\Expert2\\NBO\\Mendeleev Communications\\2013, v.23, p. 14.pdf
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22.
Инвентарный номер: нет.
   
   D 29


   
    Decarboxylation and side transamination when glutamate decarboxylase from Escherichia coli acts on substrate analogues modified at C-3 and C-4 [Text] / R. R. Khristoforov, B. S. Suchareva, H. B. F. Dixon, M. J. Sparkers, V. P. Krasnov, I. M. Bukrina, A. N. Grishakov // Biochemistry. - 1996. - Vol. 61, N 3. - P343-348
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The interaction of glutamate decarboxylase with aspartate and glutamate analogues modified at C-3 and C-4 was studied. 3-Arsonoalanine, 3-phosphonoalanine, 2-amino-4-arsonobutyric acid, 2-amino-4-phospho-nobutyric acid, a mixture of diastereoisomers of 4-(methylthio)glutamic acid, and erythro-4-(methylthio)glutamic acid were shown to be poor substrates for the enzyme.

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23.
Инвентарный номер: нет.
   


   
    Design of SiO2/aminopropylsilane-modifi ed magnetic Fe3O4 nanoparticles for doxorubicin immobilization / A. M. Demin, A. V. Vakhrushev, M. S. Valova [et al.] // Russian chemical bulletin. - 2021. - Vol. 70, № 5. - P987-994
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
MAGNETIC NANOPARTICLES -- N-PHOSPHONOMETHYLIMINODIACETIC ACID -- DOXORUBICIN -- SiO2 COATING -- SORPTION
Аннотация: Surface modifi cation of magnetic nanoparticles (MNPs) with tetramethylorthosilicate and 3-aminopropyltrimethoxysilane was studied. The use of N-phosphonomethyliminodiacetic acid for the stabilization of the initial MNPs can signifi cantly increase the coating thickness and specifi c surface area of SiO2/APS-modifi ed (APS is 3-aminopropylsilane) MNPs. The possibility of sorption of antitumor drug doxorubicin (DOX) on the synthesized nanoparticles was studied. The degree of sorption of DOX increases with an increase in the specifi c surface area of the particles.

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24.
Инвентарный номер: нет.
   
   D 47


   
    Determination of enantiomeric purity of 1-substituted 3-amino-1,2-dicarba-closo-dodecaboranes by HPLC on chiral stationary phases [Electronic resource] / V. P. Krasnov, A. M. Demin, G. L. Levit, L. Sh. Sadretdinova, A. N. Grishakov, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2008. - Vol. 57, № 12. - P2535-2539
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: A determination of enantiomeric purity of 1-substituted (Me, Ph, and Pri) 3-amino-1,2dicarba-closo-dodecaboranes by HPLC on chiral Chiralcel OD-H and Chiralpac AD stationary phases involving preliminary phthaloylation of 3-aminocarboranes has been suggested as a general method

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2008, 57 (12), 2535.pdf
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25.
Инвентарный номер: нет.
   
   D 47


   
    Determination of enantiomeric purity of 1-substituted 3-amino-1,2-dicarba-closo-dodecarboranes by HPLC on chiral stationary phases [Text] : доклад, тезисы доклада / A. M. Demin, G. L. Levit, A. N. Grishakov, L. Sh. Sadretdinova, V. A. Ol'shevskaya, V. N. Kalinin, V. P. Krasnov // Euroboron 4, Bremen, Germany, 2-6 Sept. 2007 : abstr. . - Bremen, Germany, 2007. - 128 (47PO). - Bibliogr. : p. 128 (2 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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26.
Инвентарный номер: нет.
   
   D 53


   
    Diastereoselective acylation of 3,4-dihydro-3-methyl-2H-[1,4]benzoxazines with 2-phenoxy carbonyl chlorides / S. A. Vakarov, D. A. Gruzdev, L. Sh. Sadretdinova, E. N. Chulakov, M. G. Pervova, M. A. Ezhikova, M. I. Kodess, G. L. Levit, V. P. Krasnov // Tetrahedron: Asymmetry . - 2015. - Vol. 26, № 5-6. - С. 312-319
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CARBONYL CHLORIDES -- DIASTEREOSELECTIVE SYNTHESIS -- dIASTEREOSELECTIVE ACYLATION

\\\\expert2\\NBO\\Tetrahedron Asymmetry\\2015, v. 26, p.312.pdf
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27.
Инвентарный номер: нет.
   
   K 81


    Krasnov, V. P.
    Diastereoselective substitution of halogen in 4-halogeno-N-phtalil-L-glutamates [Text] / V. P. Krasnov, M. A. Koroleva // Amino Acids. - 1993. - Vol. 5, N 1. - P125
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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28.
Инвентарный номер: нет.
   
   D 62


   
    Direct diastereoselective addition of l-menthol to activated 1,2,4-triazin-5(4H)-one [Text] / O. N. Chupakhin, G. V. Zyryanov, V. L. Rusinov, V. P. Krasnov, G. L. Levit, M. A. Koroleva, M. I. Kodess // Tetrahedron Letters. - 2001. - Vol. 42, № 12. - P2393-2395
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: For the first time in a triazine series it has been found that addition of a chiral O-nucleophile, l-menthol, to the C6-unsubstituted atom of 3-phenyl-1,2,4-triazin-5(4H)-one 1 activated by aliphatic acid anhydrides proceeds diastereoselectively to form a mixture of 1-acyl-6-[(1?R,3?R,4?S)-menthyl-3?)]-3-phenyl-(6S)-1,6-dihydro-1,2,4-triazin-5(4H)-ones 2 and 1-acyl-6-[(1?R,3?R,4?S)-menthyl-3?)]-3-phenyl-(6R)-1,6-dihydro-1,2,4-triazin-5(4H)-ones 3 in which the diastereomers 2 predominate. The diastereoselectivity of the process improves as the size of the N1-acyl substituent increases????

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29.
Инвентарный номер: нет.
   
   D 98


   
    Dynamic kinetic resolution via 5(4H)-oxazolone formation [Text] : доклад, тезисы доклада / O. N. Chupakhin, V. P. Krasnov, N. Z. Solieva, E. A. Zhdanova, I. M. Bukrina, L. Sh. Sadretdinova, G. L. Levit, M. I. Kodess // XXth European Colloquium on Heterocyclic Chemistry, Stockholm,Sweden, 18-21 Aug. 2002 г. - Stockholm, 2002. - C:3
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Рубрики: ХИМИЧЕСКИЕ НАУКИ

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30.
Инвентарный номер: нет.
   
   E 27


   
    Effect of nanosized TiO2–SiO2 covalently modified by chiral molecules on the asymmetric Biginelli reaction [Electronic resource] / Yu. A. Titova, O. V. Fedorova, G. L. Rusinov, A. Yu. Vigorov, V. P. Krasnov, A. Murashkevich, V. N. Charushin // Catalysis Today. - 2015. - Vol. 241. - С. 270-274. - Bibliogr. : p. 274 (23 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
NANOOXIDE TiO2–SiO -- BIGINELLI REACTION -- ASYMMETRIC CATALYSIS
Аннотация: The method for immobilization of chiral molecules (menthol and proline derivatives) on the mixed nanooxide TiO2–SiO2 surface has been developed. The synthesized nanocomposites were used as catalysts of the Biginelli reaction. It was shown that inactive chiral molecules, when covalently bonded to the nanooxide surface, acquired properties of a chiral inducer in the asymmetric Biginelli reaction.

\\\\expert2\\nbo\\Catalysis Today\\2015, v.241, p.270.pdf
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