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История Урала
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Труды Института высокотемпературной электрохимии УрО РАН
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Труды сотрудников Института горного дела УрО РАН
Труды сотрудников Института органического синтеза УрО РАН
Труды сотрудников Института теплофизики УрО РАН
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Труды сотрудников ЦНБ УрО РАН
Публикации Черешнева В.А.
Публикации Чарушина В.Н.
Каталог библиотеки ИГД УрО РАН
Каталог библиотеки ИЭРиЖ УрО РАН
Электронная энциклопедия «Дискурсология»
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 Найдено в других БД:Каталог книг и продолжающихся изданий (36)Каталог препринтов УрО РАН (1975 г. - ) (1)Нанотехнологии (1)Труды Института высокотемпературной электрохимии УрО РАН (2)Труды сотрудников Института теплофизики УрО РАН (84)Труды сотрудников Института химии твердого тела УрО РАН (21)Расплавы (4)Публикации Черешнева В.А. (1)Публикации Чарушина В.Н. (18)Каталог библиотеки ИЭРиЖ УрО РАН (2)
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Поисковый запрос: (<.>K=NITROGEN<.>)
Общее количество найденных документов : 42
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 1-10    11-20   21-30   31-40   41-42 
1.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis and properties of water-soluble 2-aminomethylidene derivatives of 1,3-dicarbonyl compounds [Electronic resource] / D. N. Bazhin, Yu. S. Kudyakova, T. I. Gorbunova, Ya. V. Burgart, A. Ya. Zapevalov, V. I. Saloutin // Russian Journal of General Chemistry. - 2013. - Vol.83, №7. - С. 1330-1335
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
SYNTHESIS -- N,N-DIPHENYLGUANIDINE -- AMINOMETHYLIDENE
Аннотация: A series of [(2-dimethylamino)ethylamino]methylidene-1,3-dicarbonyl compounds was synthesized for the first time starting from the corresponding 2-ethoxymethylidene derivatives and N,N-dimethylethylenediamine. It was shown that further alkylation of aminomethylidene derivatives with methyl iodide occurs regioselectively at the tertiary nitrogen atom. Quaternization products obtained exhibit high corrosion inhibition of mild steel in hydrochloric acid medium

\\\\expert2\\nbo\\Russian Journal of General Chemistry\\2013, V. 83, N 7, p. 1330–1335.pdf
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2.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis and properties of isomeric pyridyl-containing chitosan derivatives [Electronic resource] / S. YU. Bratskaya, Yu. A. Azarova, A. S. Portnyagin, A. Mechaev, A. Voit, A. V. Pestov // International Journal of Biological Macromolecules . - 2013. - С. 426-432. - Bibliogr. : p. 431-432 (49 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CHITOSAN -- PHYSICAL-CHEMICAL PROPERTIES -- PYRIDYL DERIVATIVE
Аннотация: Here we report on the method of synthesis in gel of a new heterocyclic aminopolymer-N-2-(4-pyridyl)ethylchitosan (4-PEC) via direct addition of 4-vinylpyridine to chitosan that yields a derivative with the substitution degree (DS) up to 0.8. The comparison of reactivity, thermal, spectroscopic, and sorption properties of a new derivative and its isomer N-2-(2-pyridyl)ethylchitosan (2-PEC) is presented. 2-PEC has higher sorption capacity and forms more stable chelates with [PdCl4]2- and [PtCl6]2- ions than 4-PEC, but the latter shows higher selectivity to noble metals ions in the presence of Cl- ions. A gradual increase of the sorption capacities and the affinity coefficient for Cu2+ and Ni2+ in the row chitosan<4-PEC<2-PEC was related to the increase of electron donor nitrogen atoms content and chelating properties of 2-PEC. A nearly negligible increase of the 4-PEC sorption capacity for Ag+, as compared to plain chitosan, was suggested to be dependent on the difference in complexation models for 2-PEC and 4-PEC derivatives. The density functional theory (DFT) calculations have shown that the "pendant" model of the complex with Ag(I) is energetically favorable only for 2-PEC derivative, while in cases of chitosan and 4-PEC only "bridge" complexes can be formed that results in lower sorption capacity

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3.
Инвентарный номер: нет.
   
   R 30

   
    Reactions of β-azolylenamines with sulfonyl azides as an approach to N-unsubstituted 1,2,3-triazoles and ethene-1,2-diamines [Electronic resource] / I. Efimov, V. A. Bakulev, N. Beliaev, M. A. Ezhikova, W. Dehaen, P. A. Slepukhin // European Journal of Organic Chemistry. - 2014. - Vol. 2014, №17. - С. 3684-3689. - Bibliogr. : p. 3689 (49 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
AZIDES -- CYCLOADDITION -- NITROGEN HETEROCYCLES
Аннотация: The reactions of β-azolylenamines 1 with sulfonyl azides 2 in acetonitrile furnished 1H-4-(azol-5-yl)-1,2,3-triazoles 3 in yields of 52-93%. β-Benzoylenaminones and β-nitroenamine of type 1 also reacted with tosyl azide to form the same type of products 3, proving the generality and efficiency of the method for the synthesis of N-unsubstituted 1,2,3-triazoles. On the other hand, the reactions of 3-(1-aryl-1,2,3-triazol-5-yl)enamines with tosyl azide in the absence of a solvent afforded a mixture of (E)-1-dimethylamino-2-tosylaminoethenes 5 and N,N-dimethyl-N′- tosylformamidine 6 in yields of 40-50 and 20%, respectively. The formation of a variety of compounds from the reactions of enamines 1 with sulfonyl azides 2 is rationalized by the various possible transformations of the intermediate 5-dimethylamino-1,2,3-triazolines

\\\\expert2\\nbo\\European Journal of Organic Chemistry\\2014, № 17. p.3684.pdf
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4.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis of novel purin-6-yl conjugates with heterocyclic amines linked via 6-aminohexanoyl fragment [Electronic resource] / E. V. Verbitskiy, E. M. Cheprakova, P. A. Slepukhin, M. A. Kravchenko, S. N. Skornyakov, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // Mendeleev Communications. - 2015. - Vol. 25. - С. 412-414. - Bibliogr. : p. 414 (30 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
2-AMINOPURINE -- PURIN-6-YL -- HETEROCYCLIC AMINES
Аннотация: Novel conjugates of purine and 2-aminopurine linked with heterocyclic amines, including chiral derivatives of 3,4-dihydro- 2H-[1,4]benzoxazine, 3,4-dihydro-2H-[1,4]benzothiazine and 1,2,3,4-tetrahydroquinoline, by 6-aminohexanoyl fragment at the 6-position of purine moiety were obtained. For this purpose, replacement of the chlorine atom in 2-amino-6-chloropurine or 6-chloropurine by direct nucleophilic substitution reaction with 6-aminohexanamides or the coupling of 6-(purin-6-ylamino)-6- hexanoic acid with nitrogen heterocycles were used.

\\\\expert2\\nbo\\Mendeleev Communications\\2015, v.25, p. 412.pdf
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5.
Инвентарный номер: нет.
   
   A 10

   
    A Convenient Approach to CF3-Containing N-Heterocycles Based on 2-Methoxy-2-methyl-5-(trifluoromethyl)furan-3(2H)-one [Electronic resource] / D. N. Bazhin, Yu. S. Kudyakova, G. -V. Roeschenthaler, Ya. V. Burgart, P. A. Slepukhin, M. L. Isenov, V. I. Saloutin, V. N. Charushin // European Journal of Organic Chemistry. - 2015. - № 23. - С. 5236-5245. - Bibliogr. : p. 5245 (23 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
NITROGEN HETEROCYCLES -- FLUORINE -- OXYGEN HETEROCYCLES
Аннотация: New synthetic routes to trifluoromethylated N-heterocycles based on condensations of 2-methoxy-2-methyl-5-(trifluoromethyl)furan-3(2H)-one with bifunctional N-nucleophiles are described. For the first time, trifluoromethyl-containing pyrazoles, pyrazolines and isoxazolines bearing hydrazone or oxime groups could be obtained by a one-pot strategy based on reactions of 5-(trifluoromethyl)furan-3(2H)-one with two equivalents of the corresponding hydrazines or hydroxylamine in the presence of an acid. The interaction of furan-3(2H)-one with ureas proceeded under mild conditions to furnish 1H-furo[2,3-d]imidazol-2(3H)-one derivatives in good yield. Further, a trifluoromethyl-containing quinoxaline derivative was obtained by condensation of furan-3(2H)-one with ortho-phenylenediamine.

\\\\expert2\\nbo\\European Journal of Organic Chemistry\\2015, №23. p.5236-5245.pdf
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6.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis, structure and complexation of the fluorinated 1,3-enaminoketones containing at the nitrogen atom substituents with a terminal C≡C bond [Electronic resource] / E. F. Zhilina, P. A. Slepukhin, N. S. Boltacheva, M. G. Pervova, D. L. Chizhov, V. I. Filyakova, V. N. Charushin // Russian Journal of General Chemistry. - 2012. - Vol. 82, №12. - P1962-1969
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
SYNTHESIS -- NITROGEN -- TERMINAL C≡C BONDS
Аннотация: The reaction of fluorinated lithium 1,3-diketonates with propargylamine hydrochloride and 1,1,1-trifluorpentane-2,4-dione or 1,1,1-trifluoro-4-methoxypent-3-en-2-one with propargylamine and 3-aminophenylacetylene were performed to obtain fluorinated 1,3-enaminones containing at a nitrogen atom substituents with terminal C≡C bonds: (Z)-1,1,1-trifluoro-4-(2-propynylamino)-3-pentene-2-one, (Z)-1,1,2,2-tetrafluoro-5-(2-propynylamino)-4-hexen-3-one, and 4-(3-ethynylphenylamino)-1,1,1-trifluoropentyl-3-en-2-one. Reactions of 4-(3-ethynyl-phenylamino)-1,1,1-trifluoro-pentyl-3-en-2-one with Cu(II) acetate or nanosized powder of copper or its oxides led to the respective chelate complex. The structure of (Z)-1,1,2,2-tetrafluoro-5-(2-propynylamino)-4-hexen-3-one and a copper complex of 4-(3-etinilphenylamino)-1,1,1-trifluoropenta-3-en-2-one was determined by XRD

\\\\Expert2\\NBO\\Russian Journal of General Chemistry\\2012, V. 82, N 12, p. 1962–1969.pdf
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7.
Инвентарный номер: нет.
   
   T 44

   
    Thermal stability of new sorption materials based on polysiloxanes / L. K. Neudachina, A. Y. Golub, E. M. Gorbunova, Yu. G. Yatluk // Glass Physics and Chemistry. - 2011. - Vol.37, №6. - С. 603-612
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
THERMAL STABILITY -- THIOCARBAMOYLATED POLYSILOXANES -- SILOXANE MATRIX
Аннотация: The thermal stability of the unmodified, aminated, and thiocarbamoylated polysiloxanes has been studied. The siloxane matrix is stable in the temperature range up to 800°C. For the first time, mass spectrometry has been applied to the analysis of the composition of the gaseous products of thermal decomposition of the studied polysiloxanes. It has been shown that, in the process of thermal decomposition, the terminal functional groups are detached and oxidized. Water, ammonia, nitrogen, carbon, and sulfur (in the case of thiourea-modified sorbent) oxides are formed predominantly. The quantitative removal of functional groups during heating up to 800°C has been confirmed by IR spectroscopy. A mechanism of thermal decomposition of polysiloxane xerogels has been proposed. It has been found that adsorption of platinum increases the thermal stability of the samples

\\\\Expert2\\nbo\\Glass Physics and Chemistry\\2011, V. 37, N 6, P.603-612.pdf
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8.
Инвентарный номер: нет.
   
   V 29

    Varaksin, M. V.
    Direct C-C coupling of cyclic aldonitrones with 1,2,4-triazines using SN H reactions [Электронный ресурс] / M. V. Varaksin, I. A. Utepova, O. N. Chupakhin // Chemistry of Heterocyclic Compounds. - 2012. - Vol.48, №8. - P1213-1219
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
1,2,4-TRIAZINES -- ALDONITRONES -- SnH REACTIONS
Аннотация: New nitrogen heterocyclic derivatives were obtained by a direct uncatalyzed by metals C-C cross-coupling of a cyclic aldonitrone lithium derivative with 1,2,4-triazines

\\\\Expert2\\NBO\\Chemistry of Heterocyclic Compounds\\2012, v.48, N 8, p.1213-1219.pdf
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9.
Инвентарный номер: нет.
   
   P 93

   
    Protonation of 1,2,4-triazine 4-oxides [Electronic resource] / R. E. Trifonov, V. A. Ostrovskii, V. L. Rusinov, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2013. - Vol.49, №3. - С. 450-454. - Библиогр.: с. 454 (14 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
1,2,4-TRIAZINE -- N-OXIDES -- NITROGEN ATOM
Аннотация: The basicity of some 1,2,4-triazine 4-oxides was estimated on a quantitative level, and their probable protonation patterns were ascertained. The dissociation constants of mono- and diprotonated 3-R-6-phenyl-1,2,4-triazine 4-oxides in aqueous buffer solutions and aqueous sulfuric acid solutions were determined (6-phenyl-1,2,4-triazine 4-oxide: pKBH + = 1.1, pKBH 2+ = - 6.02). According to the results of DFT calculations (B3LYP/6-311**) and spectral data, first protonation of 1,2,4-triazine 4-oxides involves the N1 nitrogen atom, and the second proton adds to the N-oxide oxygen a

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10.
Инвентарный номер: нет.
   
   W 31

   
    Water-soluble 2-aminomethylidene-1,3-dicarbonyl compounds as new chalcogenide colloidal stabilizers [Electronic resource] / D. N. Bazhin, Yu. S. Kudyakova, T. I. Gorbunova, N. S. Kozhevnikova, N. S. Suntsov, Ya. V. Burgart, A. A. Rempel, G. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2013. - Vol.49, №3. - P315-320. - Библиогр.: с. 320 (21 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
NITROGEN ATOM -- N,N-DIMETHYLETHANE-1,2-DIAMINE -- CADMIUM
Аннотация: Reactions of 2-ethoxymethylidene derivatives of 1,3-dicarbonyl compounds with N,N-dimethylethane-1,2-diamine gave a number of 2-[(2-dimethylaminoethyl)amino]methylidene-1,3-dicarbonyl compounds which were subjected to regioselective quaternization at the tertiary nitrogen atom with methyl iodide. The resulting quaternary ammonium salts inhibited aggregation of cadmium and zinc sulfide sols in aqueous medium

\\\\expert2\\NBO\\Russian Journal of Organic Chemistry\\2013, 49, (3), 315-320.pdf
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