Центральная Научная Библиотека УрО РАН

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   D 49


    Development of certified reference samples of solutions of trihalomethanes [Electronic resource] / V. E. Kirichenko, M. G. Pervova, K. I. Pashkevich, I. A. Piterskikh // Journal of Analytical Chemistry. - 2000. - Vol. 55, N 3. - P221-226

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

\\\\Expert2\\nbo\\Journal of Analytical Chemistry\\2000, V. 55, N 3, p. 221.pdf
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   C 41


    Certified reference samples of tetrachloromethane, tetrachloroethylene, and chlorophenol solutions [Electronic resource] / I. A. Piterskikh, V. E. Kirichenko, M. G. Pervova, K. I. Pashkevich // Journal of Analytical Chemistry. - 2000. - Vol. 55, N 3. - P227-230

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

\\\\Expert2\\nbo\\Journal of Analytical Chemistry\\2000, V. 55, N 3, p. 227.pdf
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   K 48

    Kirichenko, V. E.
    The comparsion of approaches for determinations of phenols as derivatives [Text] : доклад, тезисы доклада / V. E. Kirichenko, M. G. Pervova, K. I. Pashkevich // International Congress of Analitical Chemistry, M., June 15-21, 1997 : absracts. - M., 1997. - Vol. 1. - PE89

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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   S 98


    Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins [Electronic resource] / L. V. Saloutina, A. Ya. Zapevalov, V. I. Saloutin, M. I. Kodess, V. E. Kirichenko, M. G. Pervova, O. N. Chupakhin // Journal of Fluorine Chemistry. - 2005. - Vol. 126, № 6. - P976-983

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of oxides of internal trans-, cis-perfluoroolefins with o-phenylenediamine and 2-aminophenol in dioxane gave 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-2H-1,4-benzoxazin-2-ols respectively in yields of 23–67%. When N,N-dimethylacetamide was used as a solvent an anionic isomerization of the oxides into ketones, which further yielded 2-(perfluoroalkyl)benzimidazoles in the case of o-phenylenediamine and 2-hydroxy-N-perfluoroalkanoylanilines in the case of 2-aminophenol, became the main path of these reactions. Unusual cyclization resulting in 2-pentafluoroethyl-2-pentafluoropropanoylbenzoxazolidine occurs on interaction between dodecafluoro-3,4-epoxyhexane and 2-aminophenol in N,N-dimethylacetamide.

\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2005, v.126, p.976.pdf
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   R 30


    Reactivity of congeners of Sovol technical mixture of polychlorinated biphenyls toward sodium methoxide [Electronic resource] / O. N. Zabelina, T. I. Gorbunova, M. G. Pervova, V. E. Kirichenko, A. Ya. Zapevalov, V. I. Saloutin, O. N. Chupakhin // Russian Journal of Applied Chemistry. - 2004. - Vol. 77, № 9. - P1523-1527. - Библиогр. : с. 1527 (6 назв.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reaction of Sovol technical mixture of polychlorobiphenyls with sodium methoxide in bipolar aprotic solvents was studied. The reactivity of polychlorobiphenyls was evaluated using gas chromatography and gas chromatography-mass spectrometry.

\\\\Cserver\\dist\\НБО\\Электронная библиотека_Библиогр1\\Russian Journal of Applied Chemistry\\2004, v. 77, N. 9 p.1523.pdf
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   A 10


    A route to fluorocontaining N,S-heterocycles via octafluoro-2,3-epoxybutane [Text] / L. V. Saloutina, A. Ya. Zapevalov, V. I. Saloutin, P. A. Slepukhin, M. I. Kodess, V. E. Kirichenko, M. G. Pervova, O. N. Chupakhin // Journal of Fluorine Chemistry. - 2007. - Vol. 128, № 7. - P769-778

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reaction of octafluoro-2,3-epoxybutane 1 with 2-aminothiophenol gave three kinds of novel fluorocontaining N,S-heterocyclic compounds depending on the solvent nature: 2,3-bis(trifluoromethyl)-3,4-dihydro-2H-1,4-benzothiazin-2-ol 2, 2-trifluoromethyl-2-[1-(2-aminophenylthio)-2,2,2-trifluoroethyl]-1,3-benzothiazolidine 6 and 5a,11a-bis(trifluoromethyl)-5a,6,11a,12-tetrahydro-5,11-dithia-6,12-diazanaphthacene 5. Use of the toluene, dioxane, tetrahydrofuran, acetonitrile and dimethoxyethane gave the unexpected dihydrobenzothiazine 2 (RS,SR RR,SS) in good to moderate yields. In dimethylsulfoxide and N,N-dimethylacetamide, unusual cyclization occurred resulting in benzothiazolidine 6 (RS,SR/RR,SS 1:1) in moderate yields. Formation of minor 1,1,1,3,4,4,4-heptafluoro-3-(2-aminophenylthio)-2,2-dihydroxybutane 4 which was converted into bis(benzothiazine) 5 was observed in all solvents tested with the exception of toluene and dioxane. The molecular structure of the RS,SR-diastereomer of dihydrobenzothiazine 2, bis(benzothiazine) 5 and the RS,SR-diastereomer of benzothiazolidine 6 has been established by X-ray crystallography.

\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2007, v.128. p.769.pdf
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   R 30


    Reaction of 2,3-epoxyoctafluorobutane with 2-aminobenzenethiol [Electronic resource] / L. V. Saloutina, A. Ya. Zapevalov, V. I. Saloutin, M. I. Kodess, V. E. Kirichenko, M. G. Pervova, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2006. - Vol. 42, № 9. - P1307-1312. - Bibliogr. : p. 1312 (13 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
2,3-EPOXYOCTAFLUOROBUTANE -- 2-AMINOBENZENETHIOL -- EPOXY RING
Аннотация: The reaction of 2,3-epoxyoctafluorobutane with 2-aminobenzenethiol in N,N-dimethylacetamide gave 3-(2-aminophenylsulfanyl)-1,1,1,3,4,4,4- heptafluorobutane-2,2-diol. In the reaction of the same compounds in dioxane, 2,3-bis(trifluoromethyl)-3,4-dihydro-2H-1,4-benzothiazin-2-ol was formed as a result of primary attack by the amino group in 2-aminobenzenethiol on the epoxy ring. The same product was obtained by treatment with 2-aminobenzenethiol of 2,3-bis(trifluoromethyl)-2H-1,4-benzoxazin-2-ol which was synthesized from 2,3-epoxyoctafluorobutane and 2-aminophenol.

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2006, 42 (9), 1307.pdf
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   P 93


    Products of the reaction of polychlorinated biphenyls with ethanol and potassium hydroxide in dimethyl sulfoxide [Electronic resource] / O. N. Zabelina, V. E. Kirichenko, M. G. Pervova, Yu. G. Yatluk, V. I. Saloutin // Russian Journal of Applied Chemistry. - 2006. - Vol. 79, № 5. - P791-798. - Bibliogr. : p. 798 (8 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BIPHENYLS -- ETHANOL -- POTASSIUM HYDROXIDE -- DIMETHYL SULFOXIDE -- GAS CHROMATOGRAPHY -- GAS CHROMATOGRAPHY MASS SPECTROMETRY
Аннотация: The reaction of a technical mixture of polychlorinated biphenyls with ethanol and potassium hydroxide in dimethyl sulfoxide was studied. The composition of the products formed in the process was determined by gas chromatography and gas chromatography mass spectrometry.

\\\\Expert2\\nbo\\Russian Journal of Applied Chemistry\\2006, v. 79, N. 5, p. 791.pdf
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   R 30


    Reactions of epoxides derived from internal perfluoroolefins with o-phenylenediamine and 2-aminophenol [Electronic resource] / L. V. Saloutina, A. Ya. Zapevalov, V. I. Saloutin, M. I. Kodess, V. E. Kirichenko, M. G. Pervova, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2006. - Vol. 42, № 4. - P558-566

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of epoxy derivatives of internal perfluoroolefins with o-phenylenediamine and 2-aminophenol in dioxane gave 23–67% of the corresponding 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-2H-1,4-benzoxazin-2-ols, respectively. When N,N-dimethylacetamide was used as a solvent, the main reaction pathway was anionic isomerization of epoxides into ketones which were then converted into 2-perfluoroalkylbenzimidazoles (in the reactions with o-phenylenediamine) or 2-hydroxy-N-perfluoroalkanoylanilines (in the reactions with 2-aminophenol). The reaction of 3,4-epoxydodecafluorohexane with 2-aminophenol in N,N-dimethylacetamide was accompanied by unusual cyclization to afford 2-pentafluoropropanoyl-2-pentafluoroethyl-1,3-benzoxazolidine

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2006, 42 (4), 558.pdf
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10.

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   S 98


    Synthesis and GC-MS study of fluorinated esters derived from thrimethylolpropane [Electronic resource] / M. G. Pervova, V. E. Kirichenko, T. I. Gorbunova, A. Ya. Zapevalov, V. I. Saloutin // Russian Journal of General Chemistry. - 2008. - Vol. 78, № 9. - P1701-1706

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Zol-gel process was used to synthesize equilibrium mixtures of mono-, di-, and trimester derived from trimethylolpropane and perfluorocarboxylic acids. The elution order of the components of the mixtures from a weakly polar HP-5 column was established. The mass spectra of the synthesized compounds were studied. The GC-MS parameters of the products were compared with the respective parameters of their nonfluorinated analogs. The characteristics of the fluorinated esters have features determined by the esterification degree and the nature of the perfluoroalkyl groups, due to which these compounds can be identified in mixtures

\\\\Expert2\\nbo\\Russian Journal of General Chemistry\\2008, V. 78, N 9, p.1701.pdf
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11.

Инвентарный номер: нет.

   P 48

    Pervova, M. G.
    Determination of 1,2,3-benzotriazole in aqueous solutions and air by reaction-gas-liquid chromatography [Electronic resource] / M. G. Pervova, V. E. Kirichenko, V. I. Saloutin // Journal of Analytical Chemistry. - 2010. - Vol. 65, № 3. - P276-279 : табл., граф. - Bibliogr. : p. 279 (18 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BENZOTRIAZOLE -- AQUEOUS SOLUTIONS -- AIR -- CHROMATOGRAPHY -- REACTION-GAS-LIQUID CHROMATOGRAPHY
Аннотация: A procedure is developed for the gas-chromatographic determination of 1,2,3-benzotriazole including preliminary derivatization with acetic anhydride in an aqueous solution followed by the extraction the derivative with toluene. The procedure is applied to the analysis of water samples, process solutions for treating metals, air of the working zone, and industrial emissions. Determination limits in water media are 0.01 mg/L and in the air of the working zone, 0.1 mg/m3.

\\\\Expert2\\nbo\\Journal of Analytical Chemistry\\2010, V. 65, N 3, p. 276-279.pdf
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12.

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   I-69


    Interstate certified reference material for composition of p-bromoanilide of tetrafluoropropionic acid for the purposes of element analysis of organic compounds [Text] : доклад, тезисы доклада / L. N. Bazhenova, V. E. Kirichenko, M. G. Pervova, E. V. Ratnikova, L. M. Somova, I. V. Schur, T. M. Malygina // International Congress on Analytical Sciences "ICAS - 2006", M., June 25-30 2006 : book of abstracts. - M., 2006. - Vol. 1. - P153

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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13.

Инвентарный номер: нет.

   P 48

    Pervova, M. G.
    Determination of Chloroacetic Acids in Drinking Water by Reaction Gas Chromatography [Electronic resource] / M. G. Pervova, V. E. Kirichenko, K. I. Pashkevich // Journal of Analytical Chemistry. - 2002. - Vol. 57, № 4. - P326-330. - Bibliogr. : p. 330 (20 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: A procedure was developed for determining chloroacetic acids in drinking water. The procedure is based on solid-phase extraction followed by the conversion of chloroacetic acids to trifluoroacetic esters and their separation and determination by gas–liquid chromatography with an electron capture detector. Esterification conditions were optimized. The procedure was used for analyzing samples of drinking water

\\\\Expert2\\nbo\\Journal of Analytical Chemistry\\2002, V. 57, N 4, p. 326.pdf
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14.

Инвентарный номер: нет.

   T 86


    Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N?-1,2-phenylen-bis(beta-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes [Text] / D. L. Chizhov, M. G. Pervova, M. A. Samorukova, E. F. Khmara, V. I. Filyakova, V. I. Saloutin, V. N. Charushin // Journal of Fluorine Chemistry. - 2011. - Vol. 132, № 6. - P394-401. - Bibliogr. : p. 401 (19 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: An effecient synthetic method for fluorinated tridentate ?-aminoenones and tetradentate bis(?-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(?-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described

\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2011, v. 132, p.394.pdf
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15.

Инвентарный номер: нет.

   S 89


    Structure and characteristics of chitosan cobalt-containing hybrid systems, the catalysts of olefine oxidation [Electronic resource] / A. V. Mekhaev, A. V. Pestov, L. S. Molochnikov, E. G. Kovaleva, M. G. Pervova, Yu. G. Yatluk, I. A. Grigor'ev, I. A. Kirilyuk // Russian Journal of Physical Chemistry A, Focus on Chemistry. - 2011. - Vol. 85, № 7. - P1155-1161. - Bibliogr. : p. 1160-1161 (18 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Cobalt-containing hybrid organo-inorganic materials based on the chitosan-SiO2, chitosan-Al2O3, and chitosan-cellulose systems were obtained. The surface structure and processes that occur during the formation of metal-containing materials, the catalytic properties of which were studied in the oxidation reactions of alkene, were investigated by EPR spectroscopy using a stable pH-sensitive nitroxyl radical, 4-dimethylamino-2-ethyl-5,5-dimethyl-2-(pyridin-4-yl)-2,5-dihydro-1H-imidazole-1-oxyl, as the adsorbed probe molecules

\\\\Expert2\\nbo\\Russian Journal of Physical Chemistry A, Focus on Chemistry\\2011, V.85, N 7, p.1155.pdf
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16.

Инвентарный номер: нет.

   A 10


    A new anionic palladium(II) complex as a highly efficient cross-coupling catalyst [Text] : доклад, тезисы доклада / A. Mechaev, A. V. Pestov, Yu. G. Yatluk, M. G. Pervova, O. N. Chupakhin // 3rd EuCheMS Chemistry Congress "Chemistry - the Creative Force", Nuremberg, 29 august-02 ceptember2010. - Nuremberg, 2010. - P1353 : il.

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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17.

Инвентарный номер: нет.

   R 30


    Reactions of 5-(het)aryl-1-ethyl-2(1H )-pyrazinones with terminal arylacetylenes promoted by microwave radiation / E. V. Verbitskiy, E. M. Cheprakova, P. A. Slepukhin, M. G. Pervova, M. A. Samorukova, O. N. Zabelina, G. L. Rusinov, V. N. Charushin // Chemistry of Heterocyclic Compounds. - 2011. - Vol. 47, № 6. - P710-718. - Bibliogr. : p. 718 (13 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ARYLACETYLENES -- MICROWAVE RADIATION -- IONIC LIQUID
Аннотация: The reaction of 5-(het)aryl-1-ethyl-2(1H)-pyrazinones with terminal arylacetylenes, leading to a mixture of two isomeric 4-aryl- and 5-aryl-substituted 2(1H)-pyridones has been investigated. The regioselectivity of this reaction has been shown on the basis of reaction mixtures study by chromato-mass spectrometry. A crystallographic investigation of the synthesized 2(1H)-pyridones and also a forecast of their potential biological activity have been carried out

\\\\Expert2\\nbo\\Chemistry of Heterocyclic Compounds\\2011, v.47, N 6, p.710-718.pdf
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18.

Инвентарный номер: нет.

   R 30


    Reactivity features of polychlorobiphenyl congeners in the nucleophilic substitution reactions / T. I. Gorbunova, M. G. Pervova, V. I. Saloutin, O. N. Chupakhin // Russian Journal of General Chemistry. - 2012. - Vol. 82, № 1. - С. 138-143. - Bibliogr. : p. 143 (18 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
POLYCHLORINATED-BIPHENYLS -- IRON -- DECHLORINATION -- NANOPARTICLES -- PCBS
Аннотация: Groups of congeners and individual congeners of polychlorobiphenyls contributing to the composition of the technical mixture "Sovol" (PCB 60, PCB 64, PCB 70, PCB 74, PCB 97, PCB 101, PCB 105, PCB 110, PCB 118, PCB 138, PCB 149, PCB 156, and PCB 163) were synthesized by the reaction of aryl-aryl coupling. The interaction of the congeners with sodium methoxide was performed and their complete conversion was proved. By means of gas chromatography-mass spectrometry the PCBs methoxy derivatives were identified. The data on the reactivity of the individual polychlorobiphenyl congeners were precised

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19.

Инвентарный номер: нет.

   P 17


    Palladium complex of 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one: Synthesis, structure, and catalytic activity / A. Mechaev, A. V. Pestov, P. A. Slepukhin, Yu. G. Yatluk, M. G. Pervova, M. A. Samorukova, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2011. - Vol.47, №9. - С. 1366-1369

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
HECK REACTION -- ARYL
Аннотация: Palladium(II) complex with 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one was synthesized for the first time. The ligand was prepared from 3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one and 4-methylphenol via nucleophilic substitution of hydrogen (S (N) (H) reaction). The complex was readily soluble in basic medium, and it effectively catalyzed Mizoroki-Heck reaction

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2011, 47 (9), 1366.pdf
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20.

Инвентарный номер: нет.

   C 73


    Combination of the Suzuki–Miyaura cross-coupling and nucleophilic aromatic substitution of hydrogen (HSN) reactions as a versatile route to pyrimidines bearing thiophene fragments / E. V. Verbitskiy, E. M. Cherprakova, P. A. Slepukhin, M. I. Kodess, M. A. Ezhikova, M. G. Pervova, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // Tetrahedron. - 2012. - Vol.68, №27-28. - С. 5445-5452

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
SUZUKI–MIYAURA -- CROSS-COUPLING -- PYRIMIDINES
Аннотация: It has been shown that combination of the Suzuki–Miyaura cross-coupling and nucleophilic aromatic substitution of hydrogen is a versatile method for the synthesis of 4-(thiophen-2-yl)-, 5-(thiophen-2-yl)-, and 4,5-di(thiophen-2-yl) substituted pyrimidines from the commercially available 5-bromopyrimidine. The HSN (AE)- and HSN (AO)-reactions of 5-bromopyrimidine with thiophene and 2-bromothiophene have been studied by gas–liquid chromatography/mass-spectrometry. The structures of intermediate σH-adducts, as well as thiophene-(thiophenyl)pyrimidine and bithiophene-(thiophenyl)pyrimidine dyads have first been established by X-ray crystallography analysis

\\\\Expert2\\nbo\\Tetrahedron\\2012, v. 68, p. 5445.pdf
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21.

Инвентарный номер: нет.

   C 75


    Consecutive S-N(H) and Suzuki–Miyaura Cross-Coupling Reactions – an Efficient Synthetic Strategy to Pyrimidines Bearing Pyrrole and Indole Fragments / E. V. Verbitskiy, G. L. Rusinov, V. N. Charushin, O. N. Chupakhin, E. M. Cheprakova, P. A. Slepukhin, M. G. Pervova, M. I. Kodess // European Journal of Organic Chemistry. - 2012. - Vol. 2012, №33. - С. 6612-6621

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
SYNTHETIC METHODS -- CROSS-COUPLING -- NITROGEN HETEROCYCLES
Аннотация: The combination of the Suzuki–Miyaura cross-coupling and nucleophilic aromatic substitution of hydrogen reactions is a versatile tool for the syntheses of 4-(1R-pyrrol-2-yl)- and 4-(1R-indol-3-yl)-5-(hetero)aryl-substituted pyrimidines from commercially available 5-bromopyrimidine. The SNH [AE, (addition–elimination)] and SNH [AO, (addition–oxidation)] reactions of 5-bromopyrimidine with pyrroles and indoles were studied by gas chromatography–mass spectrometry. The structures of the intermediate σH adducts as well as the pyrrole-(hetero)arylpyrimidine and indole-(hetero)arylpyrimidine dyads were established for the first time by X-ray crystal structure analysis

\\\\Expert2\\nbo\\European Journal of Organic Chemistry\\2012, p.6612.pdf
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22.

Инвентарный номер: нет.

   F 33


    Features of the reaction of 3(5)-methyl-5(3)-trifluoromethylpyrazole with chloroform. Synthesis and structure of fluorinated analogs of tris(pyrazol-1-yl)methane / N. S. Boltacheva, P. A. Slepukhin, M. G. Pervova, M. A. Samorukova, L. G. Lavrenova, V. I. Filyakova, V. N. Charushin // Russian Journal of General Chemistry. - 2012. - Vol.82, №8. - С. 1444-1450

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CHLOROFORM -- TRIFLUOROMETHYLPYRAZOLE -- TRIS(PYRAZOL-1-YL)METHANE
Аннотация: Reaction of 3(5)-methyl-5(3)-trifluoromethylpyrazole (I) with chloroform leads to a complex mixture of compounds. The main components are {bis[(5-methyl-3-trifluoromethyl)pyrazol-1-yl](3-methyl-5-trifluoromethyl)pyrazol-1-yl}methane, bis{[(3-methyl-5-trifluoromethyl)pyrazol-1-yl](5-methyl-3-trifluoromethyl)-pyrazol-1-yl}methane, and tris[(3-methyl-5-trifluoro-methyl)pyrazol-1-yl]methane. The structure of isomeric substances was proved by XRD method

\\\\Expert2\\nbo\\Russian Journal of General Chemistry\\2012, V. 82, N 8, p. 1444–1450.pdf
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23.

Инвентарный номер: нет.

   A 10


    A new application of derivatives of polychlorobiphenyls and polyethylene glycols / T. I. Gorbunova, M. G. Pervova, E. B. Trushina, S. V. Pavlysko, A. Ya. Zapevalov, V. I. Saloutin // Russian Journal of Applied Chemistry. - 2012. - Vol.85, №10. - С. 1622-1626

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
POLYCHLOROBIPHENYLS -- POLYETHYLENE GLYCOLS -- SYNTHESIS
Аннотация: The reaction of congeners of Sovol technical mixture of polychlorobiphenyls with polyethylene glycols was studied. Mixtures of hydroxy and mono(polyethylene glycol)oxy derivatives were obtained. The mixtures synthesized, which are of low hazard, were used as additives to industrial oil to improve its tribological char

\\\\Expert2\\nbo\\Russian Journal of Applied Chemistry\\2012, v. 85, N 10, p.1662.pdf
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24.

Инвентарный номер: нет.

   R 30


    Reaction of polychlorinated biphenyls and benzenes with neopentyl glycol / M. G. Pervova, T. I. Gorbunova, M. A. Samorukova, V. I. Saloutin, O. N. Chupakhin // Russian Journal of General Chemistry. - 2012. - Vol.82, №3. - С. 428-435

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
1,2,4-TRICHLOROBENZENE -- BIPHENYLS -- SOVOL
Аннотация: The reactions of a mixture of 1,2,3- and 1,2,4-trichlorobenzene and polychlorinated biphenyls congeners of the industrial mixture Sovol with neopentyl glycol in the presence of alkali in DMSO medium was studied. In the conditions of nucleophilic substitution the aromatic compounds are converted completely. Using the method of gas chromatography with flame ionization and mass spectrometric detectors the structure of all synthesized compounds was studied and the following series of increasing reactivity of the polychlorinated biphenyls congeners was revealed: tetra- < penta- < hexachlorobiphenyls. The process can serve as a preliminary step of the preparation of industrial waste for the subsequent biological degradation

\\\\Expert2\\nbo\\Russian Journal of General Chemistry\\2012, V. 82, N3, p. 428-435.pdf
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25.

Инвентарный номер: нет.

   S 98


    Synthesis, structure and complexation of the fluorinated 1,3-enaminoketones containing at the nitrogen atom substituents with a terminal C≡C bond [Electronic resource] / E. F. Zhilina, P. A. Slepukhin, N. S. Boltacheva, M. G. Pervova, D. L. Chizhov, V. I. Filyakova, V. N. Charushin // Russian Journal of General Chemistry. - 2012. - Vol. 82, №12. - P1962-1969

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
SYNTHESIS -- NITROGEN -- TERMINAL C≡C BONDS
Аннотация: The reaction of fluorinated lithium 1,3-diketonates with propargylamine hydrochloride and 1,1,1-trifluorpentane-2,4-dione or 1,1,1-trifluoro-4-methoxypent-3-en-2-one with propargylamine and 3-aminophenylacetylene were performed to obtain fluorinated 1,3-enaminones containing at a nitrogen atom substituents with terminal C≡C bonds: (Z)-1,1,1-trifluoro-4-(2-propynylamino)-3-pentene-2-one, (Z)-1,1,2,2-tetrafluoro-5-(2-propynylamino)-4-hexen-3-one, and 4-(3-ethynylphenylamino)-1,1,1-trifluoropentyl-3-en-2-one. Reactions of 4-(3-ethynyl-phenylamino)-1,1,1-trifluoro-pentyl-3-en-2-one with Cu(II) acetate or nanosized powder of copper or its oxides led to the respective chelate complex. The structure of (Z)-1,1,2,2-tetrafluoro-5-(2-propynylamino)-4-hexen-3-one and a copper complex of 4-(3-etinilphenylamino)-1,1,1-trifluoropenta-3-en-2-one was determined by XRD

\\\\Expert2\\NBO\\Russian Journal of General Chemistry\\2012, V. 82, N 12, p. 1962–1969.pdf
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26.

Инвентарный номер: нет.

   M 65


    Microwave-assisted palladium-catalyzed C–C coupling versus nucleophilic aromatic substitution of hydrogen (SNH) in 5-bromopyrimidine by action of bithiophene and its analogues [Электронный ресурс] / E. V. Verbitskiy, E. M. Cheprakova, E. F. Zhilina, M. I. Kodess, M. A. Ezhikova, M. G. Pervova, P. A. Slepukhin, V. N. Charushin // Tetrahedron. - 2013. - Vol.69, №25. - P5164-5172

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
C–H BOND ACTIVATIONS -- PYRIMIDINES -- PALLADIUM
Аннотация: 5-Bromopyrimidine reacts with 2,2′-bithiophene, [2,2′:5′,2″]terthiophene and 2-phenylthiophene in the presence of a palladium catalyst to give 5-(het)aryl substituted pyrimidines due to the palladium-catalyzed aryl–aryl C–C coupling. However 5-bromo-4-(het)aryl-pyrimidines have been prepared from the same starting materials through the SNH-reaction catalyzed by a Lewis acid. Conditions for both types of reactions were optimized. All components of the reaction mixtures, including by-products, have been elucidated by gas–liquid chromatography/mass-spectrometry. Evidence for the structure of 4- and 5-bithiophenyl-substituted pyrimidines has first been obtained by means of X-ray crystallography analysis. Molecular orbital calculations (TDDFT), as well as the redox and optical measurements for all new compounds have also been performed

\\\\Expert2\\NBO\\Tetrahedron\\2013, v. 68, p. 5164.pdf
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27.

Инвентарный номер: нет.

   P 99


    Pyrolysis of polystyrene in coal tar and ethylene tar pitches [Электронный ресурс] / E. Andreikov, I. S. Amosova, Yu. A. Dikovinkina, O. Krasnikova, M. G. Pervova // Russian Journal of Applied Chemistry. - 2012. - Vol.85, №1. - P89-97

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PYROLYSIS -- POLYSTYRENE -- ETHYLENE
Аннотация: Pyrolysis of polystyrene in the medium of coal tar pitch and of pitch prepared from ethylene production tar was performed in the temperature range 360-420°C at atmospheric pressure

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28.

Инвентарный номер: нет.

   C 21


    Carboxyethenylation of polychlorobiphenyls / A. Mechaev, A. V. Pestov, Yu. G. Yatluk, M. G. Pervova, A. A. Panyukova // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2013. - Vol.49, №5. - С. 691-695. - Библиогр.: с. 695 (12 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BUTYL ACRYLATE -- PALLADIUM CATALYSTS -- POLYCHLOROBIPHENYLS
Аннотация: For the first time 2-carboxyethenylation was performed with butyl acrylate in the presence of palladium catalysts of bromine derivatives of polychlorobiphenyls obtained by bromination of polychlorobiphenyls. The haloderivatives of the butyl phenylcinnamate are readily hydrolyzed and hydrodehalogenized affording a mixture of phenylhydrocinnamic acids

\\\\expert2\\NBO\\Russian Journal of Organic Chemistry\\2013, 49, (5), 691-695.pdf
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29.

Инвентарный номер: нет.

   K 96

    Kuznetsov, V. A.
    Synthesis of epsilon-caprolactone with stable hydrogen peroxide adducts / V. A. Kuznetsov, M. G. Pervova, Yu. G. Yatluk // Russian Journal of Applied Chemistry. - 2013. - Vol.86, №2. - С. 176-181. - Библиогр.: с. 181 (16 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CYCLOHEXANONE -- E-CAPROLACTONE -- HEXAFLUOROISOPROPANOL
Аннотация: Oxidation of cyclohexanone to ɛ-caprolactone with stable industrially manufactured hydrogen peroxide derivatives: adduct with urea (urea hydrogen peroxide), sodium perborate, sodium percarbonate (Persol), magnesium monoperphthalate (Dismozon) was studied. Oxidation with urea hydrogen peroxide is the most efficient in hexafluoroisopropanol in the case of preliminary removal of urea in the form of an oxalate. Oxidation with sodium perborate and percarbonate provides high yields in trifluoroacetic acid. The lowest cost process consists in interaction with sodium monoperphthalate (Persol and phthalic anhydride) in an aqueous medium

\\\\expert2\\NBO\\Russian Journal of Applied Chemistry\\2013, v. 86, N 2, p.176.pdf
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30.

Инвентарный номер: нет.

   N 52


    New synthesis of Dialkyl carbonates from alkylene carbonates and titanium alkoxides [Electronic resource] / V. A. Kuznetsov, A. V. Pestov, M. G. Pervova, Yu. G. Yatluk // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2013. - Vol.49, №7. - С. 1078-1079. - Bibliogr. : p. 1079 (9 ref.)

ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
TITANIUM ALKOXIDES -- CARBONATES -- ALKYLENE CARBONATES

\\\\expert2\\NBO\\Russian Journal of Organic Chemistry\\2013, 49, (7), 1078-1079.pdf
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1-30 31-59

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