R 30 Reaction of fullerene C60 with 2-azido-4,6-diphenylpyrimidine [Electronic resource] / I. P. Romanova, G. G. Yusupova, D. G. Yakhvarov, O. A. Larionova, N. N. Mochul`skaya, L. P. Sidorova, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2003. - Vol. 52, № 10. - P2171-2174 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The first representative of the pyrimidine-substituted [60]fullereno[1,2-b]aziridines was synthesized by the reaction of fullerene C60 with 2-azido-4,6-diphenylpyrimidine. 2-(Azahomo[60]fullereno)-4,6-diphenylpyrimidine was found to be formed as a by-product. The electrochemical properties of the adducts were studied \\\\Expert2\\nbo\\Russian Chemical Bulletin\\2003, 52 (10), 2171.pdf |
S 98 Synthesis, structure, electrochemical and magnetic properties of 2,6-bis(5-trifluoromethylpyrazol-3-yl)pyridine and its NiII complexes [Электронный ресурс] / E. F. Khmara, D. L. Chizhov, A. A. Sidorov, G. G. Aleksandrov, P. A. Slepukhin, K. L. Tokarev, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2012. - Vol.61, №2. - P313-325 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ELECTROCHEMISTRY -- NICKEL COMPLEXES -- X-RAY DIFFRACTION ANALYSIS Аннотация: 2,6-Bis(5-trifluoromethylpyrazol-3-yl)pyridine (H2L) and its mono-, tri-, and tetranuclear NiII complexes were synthesized for the first time. All the obtained compounds were characterized by single-crystal X-ray diffraction analysis. In the complexes, 2,6-bis(5-trifluoromethylpyrazol-3-yl) pyridine exists in the neutral and dianionic forms and exhibits different coordination modes (κ3-, μ2-κ3: κ1-, and μ3-κ3: κ1:κ1). The electrochemical and magnetic properties of all compounds were studied. The tetranuclear NiII complex with the L2- dianion is reduced in two sequential reversible one-electron steps \\\\Expert2\\NBO\\Russian Chemical Bulletin\\2012, 61 (2), 313-325.pdf |
The green chemistry paradigm in modern organic synthesis / S. G. Zlotin, K. S. Egorova, V. P. Ananikov [et al.] // Russian Chemical Reviews. - 2023. - Vol. 92. - RCR5104 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ХИМИЯ ЗЕЛЕНАЯ -- СИНТЕЗ ОРГАНИЧЕСКИЙ Аннотация: After the appearance of the green chemistry concept, which was introduced in the chemistry vocabulary in the early 1990s, its main statements have been continuously developed and modified. Currently, there are 10–12 cornerstones that should form the basis for an ideal chemical process. This review analyzes the accumulated experience and achievements towards the design of chemical products and processes that reduce or eliminate the use or generation of hazardous substances. The review presents the views of leading Russian scientists specializing in various fields of this subject, including homogeneous and heterogeneous catalysis, fine and basic organic synthesis, electrochemistry, polymer chemistry, chemistry based on bio-renewable feedstocks and chemistry of energetic compounds and materials. A new approach to the quantitative evaluation of the environmental friendliness of processes developed by Russian authors is described. |