S 98 Synthesis of Functionalized Fluorescent Europium(III) Terpyridyl Chelates [Text] / V. N. Kozhevnikov, D. N. Kozhevnikov, V. L. Rusinov, O. N. Chupakhin, B. Konig // Synthesis. - 2003. - № 15. - P2400-2404. - Bibliogr. : p. 2404 (19 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): DIELS-ALDER REACTION -- HETEROCYCLES -- LANTHANIDE -- LIGANDS -- PYRIDINES -- EUROPIUM Аннотация: The synthesis of substituted terpyridines via triazine intermediates is described. The intermediates allow the facile introduction of cyano groups, which are converted into amino diacetic acid moieties. Together with the terpyridine nitrogen atoms they shield coordinated europium(III) ions completely from the solvent. The terpyridines may be further functionalized for specific applications using ligands, bromo substituents, and standard transition metal mediated coupling methods. This makes the title compounds valuable intermediates for the preparation of luminescent probes in biochemistry, medicinal diagnostics or materials science. \\\\Expert2\\nbo\\Synthesis\\2003, v.15. p.2400.Chupakhin.pdf |
U 88 Use of chiral lanthanide shift reagent in the eluidation of NMR signals from enantiomeric mixtures of 1-substituted 3-amino-1,2-dicarba-closo-dodecarboranes [Text] : доклад, тезисы доклада / M. I. Kodess, M. A. Ezhikova, G. L. Levit, V. P. Krasnov, V. N. Charushin // Euroboron 3, The 3rd European Meeting on Boron Chemistry, Pruhonice-by-Prague, Czech Republic, 12-16 Sept. 2004 : abstr. . - Pruhonice-by-Prague, Czech Republic, 2004. - P33 Рубрики: ХИМИЧЕСКИЕ НАУКИ |
U 67 Upconversion luminescence in Er3+/Yb3+ codoped Y2CaGe4O12 [Electronic resource] / I. I. Leonidov, V. G. Zubkov, A. P. Tyutyunnik, N. V. Tarakina, L. L. Surat, O. V. Koryakova, E. G. Vovkotrub // Journal of Alloys and Compounds. - 2011. - Vol. 509, № 5. - P1339-1346. - Bibliogr. : p. 1345-1346 (52 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Calcium yttrium tetrametagermanates Y2CaGe4O12 doped with Er3+ and Er3+/Yb3+ reveal upconversion emission in visible spectral range under near-infrared excitation, ex = 980 nm. For the solid solution ErxY2?xCaGe4O12 concentration dependencies for the green and red lines of the visible emission around 526 nm (2H11/2 4I15/2), 545 nm (4S3/2 4I15/2) and 670 nm (4F9/2 4I15/2) show the optimal value for the sample x = 0.2. The power dependence of the visible luminescence measured at room temperature in the low-power limit indicates two-photon upconversion process. Direct intensification of the upconversion emission signals has been achieved by ytterbium sensitizing. The other upconversion excitation mechanism in Y2CaGe4O12:Er3+ is discussed for an 808 nm incident laser irradiation. A scheme of excitation and emission routes involving ground/excited state absorption, energy transfer upconversion, nonradiative multiphonon relaxation processes in trivalent lanthanide ions in Y2CaGe4O12:Er3+ and Y2CaGe4O12:Er3+, Yb3+ has been proposed. Conditions for visible emission occurrence under quasi-resonance ex = 1064 nm excitation depending on pump power values are considered. In the low-power regime only near-infrared emission caused by the transition 4I13/2 4I15/2 in erbium ions has been detected \\\\Expert2\\nbo\\Journal of Alloys and Compounds\\2011, v.509, N 5, p.1339.pdf |
C 91 Crystal structure, spectral and thermal properties of 1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]-ethane and luminescent properties of its complexes with Al(III) and Eu(III) [Electronic resource] / L. A. Khamidullina, K. L. Obydennov, P. A. Slepukhin, I. S. Puzyrev // Journal of Molecular Structure. - 2016. - Vol. 1125. - С. 550-557 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): LANTHANIDE COMPLEXES -- ENOL-TAUTOMERISM -- BETA-DIKETONES Аннотация: Describing the crystal structure, packing, FT-IR, UV-Vis and NMR spectra and thermal properties of new polydentate O-ligand based on aryl-beta-diketone moieties connected by ethylene glycol spacer is the subject of this article. The results of IR, UV-Vis and H-1 NMR spectroscopy as well X-ray crystallography of 1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]-ethane (BTFPE) indicate that the compound exists in solution and in solid as enol. The crystal structure analysis shows that BTFPE has C2/c group of the monoclinic system. Typical S(6) intramolecular hydrogen bond occurs in each 1,3-diketo moiety. This bond is asymmetric and the H atom is closest to the 0 atom adjacent to the phenyl ring. The packing of the crystal is sustained by numerous C-H center dot center dot center dot O, O-H center dot center dot center dot F, C-H center dot center dot center dot F interactions. In the crystal, supramolecular zig-zag chains are formed along the c-axis. Short contacts interconnect the molecules into a two-dimensional layered structure wherein each molecule is node between chains. According to the thermal investigation this compound is stable up to 200 degrees C in air atmosphere, above this temperature it decomposes. Photoluminescent properties of aluminum(III) and europium(III) complexes of BTFPE were evaluated in chloroform solution and in the solid state. Aluminum complex of BTFPE shows blue luminescence with maximum at 445 nm. Europium complex exhibits intense red color luminescence at 613 nm from central Eu(III) ion through the excitation of the ligand. \\\\expert2\\NBO\\Journal of Molecular Structure\\2016, v.1125, p.550-557.pdf |
K 83 Krinochkin, A. P. Luminescent neutral lanthanide complexes of 5-aryl-2,20-bipyridine-6-carboxylic acids, synthesis and properties / A. P. Krinochkin, D. S. Kopchuk, D. N. Kozhevnikov // Polyhedron. - 2015. - Vol. 102. - С. 556-561 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): LUMINESCENT -- LANTHANIDE COMPLEXES -- SYNTHESIS \\\\expert2\\NBO\\Polyhedron\\2015, v.102, p.556.pdf |
P 91 Preparation of ligands for lanthanide cations based on 5-aryl-2,2-bipyridine-6-carboxylic acids with an extended conjugation system / A. P. Krinochkin, D. S. Kopchuk, S. Santra, G. V. Zyryanov, V. L. Rusinov, O. N. Chupakhin // Современные синтетические методологии для создания лекарственных препаратов и функциональных материалов (MOSM2018): вторая международная научно-практическая конференция : материалы и доклады. - Екатеринбург, 2019. - С. 232 Рубрики: ХИМИЧЕСКИЕ НАУКИ |