S 98 Synthesis and X-ray diffraction study of palladium(II) 1,3-diphenyl-5-(benzothiazol-2-yl)formazanate [Text] / A. V. Zaidman, I. G. Pervova, Z. G. Rezinskikh, I. N. Lipunov, P. A. Slepukhin // Crystallography Reports. - 2010. - Vol. 55, № 3. - P424-427 : рис., табл. Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The behavior of 1,3-diphenyl-5-(benzothiazol-2-yl)formazan as a bidentate ligand in the synthesis of the mononuclear palladium complex was investigated using slow diffusion. According to the X-ray diffraction study, the PdN4 coordination unit has a distorted square structure. The ligands form two six-membered chelate rings formed through the N1 and N4 atoms of the formazan fragment |
A 10 A new anionic palladium(II) complex as a highly efficient cross-coupling catalyst [Text] : доклад, тезисы доклада / A. Mechaev, A. V. Pestov, Yu. G. Yatluk, M. G. Pervova, O. N. Chupakhin // 3rd EuCheMS Chemistry Congress "Chemistry - the Creative Force", Nuremberg, 29 august-02 ceptember2010. - Nuremberg, 2010. - P1353 : il. Рубрики: ХИМИЧЕСКИЕ НАУКИ |
T 82 Trans-Dichlorobis{(1R,4S)-1,7,7-trimethyl-3-[(S)-α-methylbenzylimino]bicyclo[2.2.1]heptan-2-one-N}Palladium(II): Synthesis and structural examination [Electronic resource] / O. A. Zalevskaya, O. A. Gur'eva, L. L. Frolova, I. N. Alekseev, P. A. Slepukhin, A. V. Kuchin // Russian Journal of Coordination Chemistry. - 2013. - Vol.39, №1. - P37-40 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): PALLADIUM(II) -- SYNTHESIS -- STRUCTURAL EXAMINATION Аннотация: A reaction of (1R,4S)-1,7,7-trimethyl-3-[(S)-α-methylbenzylimino]bicyclo[2.2.1]heptan-2-one with lithium tetrachloropalladate gave a chiral palladium(II) complex with monodentate coordination of the organic ligand. The structure of the complex was confirmed by NMR spectra and X-ray diffraction data \\\\Expert2\\NBO\\Russian Journal of Coordination Chemistry\\2013, v. 39, N. 1, p.37.pdf |