R 30 Reactivity of congeners of Sovol technical mixture of polychlorinated biphenyls toward sodium methoxide [Electronic resource] / O. N. Zabelina, T. I. Gorbunova, M. G. Pervova, V. E. Kirichenko, A. Ya. Zapevalov, V. I. Saloutin, O. N. Chupakhin // Russian Journal of Applied Chemistry. - 2004. - Vol. 77, № 9. - P1523-1527. - Библиогр. : с. 1527 (6 назв.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The reaction of Sovol technical mixture of polychlorobiphenyls with sodium methoxide in bipolar aprotic solvents was studied. The reactivity of polychlorobiphenyls was evaluated using gas chromatography and gas chromatography-mass spectrometry. \\\\Cserver\\dist\\НБО\\Электронная библиотека_Библиогр1\\Russian Journal of Applied Chemistry\\2004, v. 77, N. 9 p.1523.pdf |
R 30 Reaction of dinitropolychlorobiphenyls with O- and N-nucleophiles as a new route of reprocessing polychlorobiphenyls [Electronic resource] / T. I. Gorbunova, A. Ya. Zapevalov, V. I. Saloutin, O. N. Chupakhin // Russian Journal of Applied Chemistry. - 2002. - Vol. 75, № 3. - P449-451. - Bibliogr. : p. 451 (11 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): AROMATIC COMPOUND -- DINITROPOLYCHLOROBIPHENYLS -- POLYCHLOROBIPHENYLS -- CHLORINE -- UNCLASSIFIED DRUG Аннотация: The reactivity of a mixture of dinitropolychlorobiphenyls in nucleophilic substitution of aromatic chlorine by polyethyleneoxy and amino groups was studied. New polychlorobiphenyl derivatives were obtained. \\\\Expert2\\nbo\\Russian Journal of Applied Chemistry\\2002, v. 75, N. 3, p.449.pdf |
P 91 Preparation of Amino Derivatives from Industrial Mixtures of Polychlorobiphenyls [Electronic resource] / T. I. Gorbunova, A. Ya. Zapevalov, V. E. Kirichenko, V. I. Saloutin, O. N. Chupakhin // Russian Journal of Applied Chemistry. - 2001. - Vol. 74, № 1. - P118-122. - Bibliogr. : p. 122 (16 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): AMINO DERIVATIVES -- MIXTURES -- INDUSTRIAL MIXTURES -- POLYCHLOROBIPHENYLS -- AMINOPOLYCHLOROBIPHENYLS Аннотация: Chemical utilization (conversion) of polychlorobiphenyls by nitration of their industrial mixture was studied. Reduction of the nitro derivatives gave mixtures of aminopolychlorobiphenyls. \\\\Expert2\\nbo\\Russian Journal of Applied Chemistry\\2001, v. 74, N. 1, p.118.pdf |
Г 67 Горбунова, Т. И. Химические методы превращений полихлорбифенилов [] = Chemical methods of transformation of polychlorobiphenyls / Т. И. Горбунова, В. И. Салоутин, О. Н. Чупахин // Успехи химии. - 2010. - Т. 79, № 6. - С. 565-586. - Библиогр.: с. 584-586 (123 назв.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Рассмотрены современные методы обезвреживания техногенных отходов, содержащих полихлорбифенилы. проанализированы реакционная способность отдельных конгенеров(индивидуальных компонентов) и технических смесей полихлорбифенилов в различных видах взаимодействий. оценены возможности использования производных полихлорбифенилов |
P 80 Polymers Based on Epoxy Resins and Functional Derivatives of Polychlorobiphenyls [Electronic resource] / N. Yu. Ostanina, L. D. Dultseva, A. L. Suvorov, O. N. Chupakhin // Russian Journal of Applied Chemistry. - 2002. - Vol. 75, № 5. - P814-817 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: A new way to utilize polychlorobiphenyls was suggested: transformation of Sovol base hydrolysis products into glycidyl ethers and titanates. The resulting products were tested as components of epoxy compounds which are subsequently cured to obtain three-dimensional polymer networks \\\\Expert2\\nbo\\Russian Journal of Applied Chemistry\\2002, v. 75, N. 5, p.814.pdf |
G 65 Gorbunova, T. I. Chemical methods of transformation of polychlorobiphenyls [Electronic resource] / T. I. Gorbunova, V. I. Saloutin, O. N. Chupakhin // Russian Chemical Reviews. - 2010. - Vol. 89, № 6. - P511-530 : рис. Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Modern methods for detoxication of production wastes containing polychlorobiphenyls are considered. The reactivity of some congeners (individual components) and technical mixtures of polychlorobiphenyls in various types of reactions is analyzed. The possibilities of application of polychlorobiphenyl derivatives are estimated |
R 30 Reactivity features of polychlorobiphenyl congeners in the nucleophilic substitution reactions / T. I. Gorbunova, M. G. Pervova, V. I. Saloutin, O. N. Chupakhin // Russian Journal of General Chemistry. - 2012. - Vol. 82, № 1. - С. 138-143. - Bibliogr. : p. 143 (18 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): POLYCHLORINATED-BIPHENYLS -- IRON -- DECHLORINATION -- NANOPARTICLES -- PCBS Аннотация: Groups of congeners and individual congeners of polychlorobiphenyls contributing to the composition of the technical mixture "Sovol" (PCB 60, PCB 64, PCB 70, PCB 74, PCB 97, PCB 101, PCB 105, PCB 110, PCB 118, PCB 138, PCB 149, PCB 156, and PCB 163) were synthesized by the reaction of aryl-aryl coupling. The interaction of the congeners with sodium methoxide was performed and their complete conversion was proved. By means of gas chromatography-mass spectrometry the PCBs methoxy derivatives were identified. The data on the reactivity of the individual polychlorobiphenyl congeners were precised |
A 10 A new application of derivatives of polychlorobiphenyls and polyethylene glycols / T. I. Gorbunova, M. G. Pervova, E. B. Trushina, S. V. Pavlysko, A. Ya. Zapevalov, V. I. Saloutin // Russian Journal of Applied Chemistry. - 2012. - Vol.85, №10. - С. 1622-1626 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): POLYCHLOROBIPHENYLS -- POLYETHYLENE GLYCOLS -- SYNTHESIS Аннотация: The reaction of congeners of Sovol technical mixture of polychlorobiphenyls with polyethylene glycols was studied. Mixtures of hydroxy and mono(polyethylene glycol)oxy derivatives were obtained. The mixtures synthesized, which are of low hazard, were used as additives to industrial oil to improve its tribological char \\\\Expert2\\nbo\\Russian Journal of Applied Chemistry\\2012, v. 85, N 10, p.1662.pdf |
C 21 Carboxyethenylation of polychlorobiphenyls / A. Mechaev, A. V. Pestov, Yu. G. Yatluk, M. G. Pervova, A. A. Panyukova // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2013. - Vol.49, №5. - С. 691-695. - Библиогр.: с. 695 (12 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): BUTYL ACRYLATE -- PALLADIUM CATALYSTS -- POLYCHLOROBIPHENYLS Аннотация: For the first time 2-carboxyethenylation was performed with butyl acrylate in the presence of palladium catalysts of bromine derivatives of polychlorobiphenyls obtained by bromination of polychlorobiphenyls. The haloderivatives of the butyl phenylcinnamate are readily hydrolyzed and hydrodehalogenized affording a mixture of phenylhydrocinnamic acids \\\\expert2\\NBO\\Russian Journal of Organic Chemistry\\2013, 49, (5), 691-695.pdf |