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Общее количество найденных документов : 60
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1.
Инвентарный номер: нет.
   
   C 20

   
    Capillary constant and surface tension of methane-nitrogen solutions: 1. Experiment [Electronic resource] / V. G. Baidakov, M. N. Khotienkova, V. N. Andbaeva, A. M. Kaverin // Fluid Phase Equilibria. - 2011. - Vol.301, №1. - P67-72
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
MIXTURES -- OXYGEN
Аннотация: The differential version of the method of capillary rise has been used to measure the capillary constant and calculate the surface tension of methane-nitrogen solutions. Experiments. have been conducted in the temperature range from 95 to 170K at pressures up to 4 MPa. Experimental data on surface tension have been compared with the results of calculations by thermodynamic models. Equations are given which describe the dependence of the capillary constant of a solution on its temperature and composition.

\\\\Expert2\\nbo\\Fluid Phase Equilibria\\2011, v.301, p. 67-72.pdf
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2.
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   C 20

   
    Capillary constant and surface tension of methane-nitrogen solutions: 1. Experiment [Electronic resource] / V. G. Baidakov, M. N. Khotienkova, V. N. Andbaeva, A. M. Kaverin // Fluid Phase Equilibria. - 2011. - Vol.301, №1. - P67-72
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
MIXTURES -- OXYGEN
Аннотация: The differential version of the method of capillary rise has been used to measure the capillary constant and calculate the surface tension of methane-nitrogen solutions. Experiments. have been conducted in the temperature range from 95 to 170K at pressures up to 4 MPa. Experimental data on surface tension have been compared with the results of calculations by thermodynamic models. Equations are given which describe the dependence of the capillary constant of a solution on its temperature and composition.

\\\\Expert2\\nbo\\Fluid Phase Equilibria\\2011, v.301, p. 67-72.pdf
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3.
Инвентарный номер: нет.
   
   C 20

   
    Capillary Constant of a Xenon–Helium Solution [Electronic resource] / V. G. Baidakov, A. M. Kaverin, V. N. Andbaeva, M. N. Khotienkova // Journal of Chemical & Engineering Data. - 2011. - Vol.56, №11. - P4123-4125
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CAPILLARY METHOD -- XENON–HELIUM SOLUTION
Аннотация: The differential capillary method has been used to measure the capillary constant of a xenon–helium solution. Experiments have been conducted in the temperature range from (165 to 267) K at pressures up to 4 MPa. An equation approximating the baric dependence of the capillary constant has been suggested

\\\\Expert2\\nbo\\Journal of Chemical and Engineering Data\\2011, v.56, p. 4123-4125.pdf
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4.
Инвентарный номер: нет.
   
   C 20

   
    Capillary Constant of a Xenon–Helium Solution [Electronic resource] / V. G. Baidakov, A. M. Kaverin, V. N. Andbaeva, M. N. Khotienkova // Journal of Chemical & Engineering Data. - 2011. - Vol.56, №11. - P4123-4125
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CAPILLARY METHOD -- XENON–HELIUM SOLUTION
Аннотация: The differential capillary method has been used to measure the capillary constant of a xenon–helium solution. Experiments have been conducted in the temperature range from (165 to 267) K at pressures up to 4 MPa. An equation approximating the baric dependence of the capillary constant has been suggested

\\\\Expert2\\nbo\\Journal of Chemical and Engineering Data\\2011, v.56, p. 4123-4125.pdf
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5.
Инвентарный номер: нет.
   
   B 16

    Baidakov, V. G.
    Cavitation and crystallization in a metastable Lennard-Jones liquid at negative pressures and low temperatures [Electronic resource] / V. G. Baidakov, K. S. Bobrov, A. S. Teterin // Journal of Chemical Physics. - 2011. - Vol.135, №5. - P054512
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
SOLID-LIQUIDS -- LIQUIDS -- LENNARD-JONES
Аннотация: Molecular dynamics simulations have been used to investigate the kinetics of spontaneous cavitation and crystallization in a Lennard-Jones liquid at negative pressures in the temperature range where these processes compete with each other. The nucleation rate has been calculated in NVE and NpT ensembles by the method of mean lifetime and the transition interface sampling method with parallel path swapping. The data obtained have been used to determine in the framework of classical nucleation theory the value of the ratio of the solid–liquid and the liquid–void interfacial free energy for critical crystals and cavities and the values of their volumes at points where the cavitation rate of the liquid is equal to the rate of its crystallization

\\\\Expert2\\nbo\\Journal of Chemical Physics\\2011, v.135, p.054512.pdf
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6.
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   B 16

    Baidakov, V. G.
    Cavitation and crystallization in a metastable Lennard-Jones liquid at negative pressures and low temperatures [Electronic resource] / V. G. Baidakov, K. S. Bobrov, A. S. Teterin // Journal of Chemical Physics. - 2011. - Vol.135, №5. - P054512
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
SOLID-LIQUIDS -- LIQUIDS -- LENNARD-JONES
Аннотация: Molecular dynamics simulations have been used to investigate the kinetics of spontaneous cavitation and crystallization in a Lennard-Jones liquid at negative pressures in the temperature range where these processes compete with each other. The nucleation rate has been calculated in NVE and NpT ensembles by the method of mean lifetime and the transition interface sampling method with parallel path swapping. The data obtained have been used to determine in the framework of classical nucleation theory the value of the ratio of the solid–liquid and the liquid–void interfacial free energy for critical crystals and cavities and the values of their volumes at points where the cavitation rate of the liquid is equal to the rate of its crystallization

\\\\Expert2\\nbo\\Journal of Chemical Physics\\2011, v.135, p.054512.pdf
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7.
Инвентарный номер: нет.
   
   B 93

    Bulanov, N. V.
    Characteristic features of the boiling of emulsions having a low-boiling dispersed phase [Electronic resource] / N. V. Bulanov, B. M. Gasanov // Journal of Engineering Physics and Thermophysics. - 2006. - Vol. 79, № 6. - P1130-1133
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
BOILING
Аннотация: The results of investigation of heat transfer from thin wires to a boiling emulsion, the dispersed phase of which is formed from a liquid with a boiling temperature much lower than the boiling temperature of the dispersion medium, are presented. Two variants of boiling of such an emulsion are possible: boiling of the dispersed phase alone and simultaneous boiling of the dispersed phase and dispersion medium. In the present work, only the first variant has been studied; it is distinguished by the following most important features: high superheat of the dispersed-phase droplets ?Tsup of the emulsion and a wide temperature range of bubble boiling (50–200°C). For conventional heat carriers (pure liquids and solutions), the value of ?Tsup does not exceed 1–10°C, with the bubble-boiling interval lying within the range from 5 to 20°C.

\\\\Expert2\\NBO\\Journal of Engineering Physics and Thermophysics\\2006, v.79, N 6, P.1130.pdf
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8.
Инвентарный номер: нет.
   
   B 93

    Bulanov, N. V.
    Characteristic features of the boiling of emulsions having a low-boiling dispersed phase [Electronic resource] / N. V. Bulanov, B. M. Gasanov // Journal of Engineering Physics and Thermophysics. - 2006. - Vol. 79, № 6. - P1130-1133
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
BOILING
Аннотация: The results of investigation of heat transfer from thin wires to a boiling emulsion, the dispersed phase of which is formed from a liquid with a boiling temperature much lower than the boiling temperature of the dispersion medium, are presented. Two variants of boiling of such an emulsion are possible: boiling of the dispersed phase alone and simultaneous boiling of the dispersed phase and dispersion medium. In the present work, only the first variant has been studied; it is distinguished by the following most important features: high superheat of the dispersed-phase droplets ?Tsup of the emulsion and a wide temperature range of bubble boiling (50–200°C). For conventional heat carriers (pure liquids and solutions), the value of ?Tsup does not exceed 1–10°C, with the bubble-boiling interval lying within the range from 5 to 20°C.

\\\\Expert2\\NBO\\Journal of Engineering Physics and Thermophysics\\2006, v.79, N 6, P.1130.pdf
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9.
Инвентарный номер: нет.
   
   S 34

    Schmelzer, J. W. P.
    Classical and generalized Gibbs' approaches and the work of critical cluster formation in nucleation theory [Electronic resource] / J. W. P. Schmelzer, G. Sh. Boltachev, V. G. Baidakov // Journal of Chemical Physics. - 2006. - Vol. 124, № 19. - P194503/1-194503/18
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CLUSTERS
Аннотация: In the theoretical interpretation of the kinetics of first-order phase transitions, thermodynamic concepts developed long ago by Gibbs are widely employed giving some basic qualitative insights into these processes. However, from a quantitative point of view, the results of such analysis, based on the classical Gibbs approach and involving in addition the capillarity approximation, are often not satisfactory. Some progress can be reached here by the van der Waals and more advanced density functional methods of description of thermodynamically heterogeneous systems having, however, its limitations in application to the interpretation of experimental data as well. Moreover, both mentioned theories—Gibbs’ and density functional approaches—lead to partly contradicting each other’s results. As shown in preceding papers, by generalizing Gibbs’ approach, existing deficiencies and internal contradictions of these two well-established theories can be removed and a new generally applicable tool for the interpretation of phase formation processes can be developed. In the present analysis, a comparative analysis of the basic assumptions and predictions of the classical and the generalized Gibbs approaches is given. It is shown, in particular, that—interpreted in terms of the generalized Gibbs approach—the critical cluster as determined via the classical Gibbs approach corresponds not to a saddle but to a ridge point of the appropriate thermodynamic potential hypersurface. By this reason, the classical Gibbs approach (involving the classical capillarity approximation) overestimates as a rule the work of critical cluster formation in nucleation theory and, in general, considerably.

\\\\Expert2\\NBO\\Journal of Chemical Physics\\2006, v.124, p.194503.pdf
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10.
Инвентарный номер: нет.
   
   S 34

    Schmelzer, J. W. P.
    Classical and generalized Gibbs' approaches and the work of critical cluster formation in nucleation theory [Electronic resource] / J. W. P. Schmelzer, G. Sh. Boltachev, V. G. Baidakov // Journal of Chemical Physics. - 2006. - Vol. 124, № 19. - P194503/1-194503/18
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CLUSTERS
Аннотация: In the theoretical interpretation of the kinetics of first-order phase transitions, thermodynamic concepts developed long ago by Gibbs are widely employed giving some basic qualitative insights into these processes. However, from a quantitative point of view, the results of such analysis, based on the classical Gibbs approach and involving in addition the capillarity approximation, are often not satisfactory. Some progress can be reached here by the van der Waals and more advanced density functional methods of description of thermodynamically heterogeneous systems having, however, its limitations in application to the interpretation of experimental data as well. Moreover, both mentioned theories—Gibbs’ and density functional approaches—lead to partly contradicting each other’s results. As shown in preceding papers, by generalizing Gibbs’ approach, existing deficiencies and internal contradictions of these two well-established theories can be removed and a new generally applicable tool for the interpretation of phase formation processes can be developed. In the present analysis, a comparative analysis of the basic assumptions and predictions of the classical and the generalized Gibbs approaches is given. It is shown, in particular, that—interpreted in terms of the generalized Gibbs approach—the critical cluster as determined via the classical Gibbs approach corresponds not to a saddle but to a ridge point of the appropriate thermodynamic potential hypersurface. By this reason, the classical Gibbs approach (involving the classical capillarity approximation) overestimates as a rule the work of critical cluster formation in nucleation theory and, in general, considerably.

\\\\Expert2\\NBO\\Journal of Chemical Physics\\2006, v.124, p.194503.pdf
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