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Общее количество найденных документов : 30
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1.
Инвентарный номер: нет.
   
   E 27


   
    Effects of Structural Disorder in Lithium Manganite and Titanate Oxides / Yu. G. Chukalkin, A. E. Teplykh, D. G. Kellerman, V. S. Gorshkov // Physics of the Solid State. - 2010. - vol. 52, № 5. - P1006-1009 : il. - Bibliogr. : p. 1009 (11 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
МАНГАНИТ ЛИТИЯ -- ТИТАНАТЫ -- СТЕХИОМЕТРИЯ
Аннотация: The structures and magnetic states of stoichiometric lithium manganite LiMn2O4 and manganites and titanates Li1.33Mn1.67O4 and Li1.33Ti1.67O4 with excess lithium in both the initial (as-synthesized) state and after irradiation by fast (Eeff ≥ 1 MeV) neutrons with a fluence of 2 × 1020 cm–2 have been studied using neutron diffraction, X-ray diffraction, and magnetic methods. It has been established that the irradiation brings about a noticeable redistribution of manganese, titanium, and lithium cations over nonequivalent tetrahedral (8a) and octahedral (16d) positions of a spinel lattice. This structural disorder causes a radical change in the physical properties of the materials under study. The charge order existing in the initial LiMn2O4 sample is destroyed. There arises a strong intersublattice indirect exchange interaction Mn(8a)–O–Mn(16d). The disorder is accompanied by the antiferromagnet–ferrimagnet (LiMn2O4) and paramagnet–ferrimagnet (Li1.33Mn1.67O4) magnetic transitions

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2.
Инвентарный номер: нет.
   
   O-66


   
    Optical Absorption and Nuclear Magnetic Resonance in Lithium Titanium Spinel Doped by Chromium / D. G. Kellerman, N. A. Mukhina, N. A. Zhuravlev, M. S. Valova, V. S. Gorshkov // Physics of the Solid State. - 2010. - Vol. 52, № 3. - P459-464 : il. - Bibliogr. : p. 463-464 (34 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ОПТИЧЕСКАЯ АБСОРБЦИЯ -- ЯМР -- ЯДЕРНЫЙ МАГНИТНЫЙ РЕЗОНАНС -- ТИТАНАТ ЛИТИЯ -- ШПИНЕЛИ -- ДОПИРОВАНИЕ -- ХРОМ
Аннотация: The optical absorption and nuclear magnetic resonance spectra of Li4 – xCr3xTi5 – 2xO12 (x = 0, 0.01, 0.02, 0.04) solid solutions have been investigated. It has been found that, in the Li4Ti5O12 spinel, lithium ions migrate from tetrahedral to octahedral positions with increasing temperature. Doping of chromium to the spinel favors an increase in the fraction of tetrahedrally coordinated lithium and hinders diffusion

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3.
Инвентарный номер: нет.
   
   M 17


   
    Magnetism of LiMn2O4 Manganite in Structurally Ordered and Disordered States / Yu. G. Chukalkin, A. E. Teplykh, A. N. Pirogov, D. G. Kellerman // Physics of the Solid State. - 2010. - vol. 52, № 12. - P2545-2551 : il. - Bibliogr. : p. 2551 (17 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
МАГНЕТИЗМ -- МАНГАНИТ ЛИТИЯ -- СТЕХИОМЕТРИЯ
Аннотация: The specific features of the crystal structure and the magnetic state of stoichiometric lithium man ganite in the structurally ordered Li[Mn2]O4 and disordered Li1 – δMnδ[Mn2 – δLiδ]O4 (δ = 1/6) states have been investigated using neutron diffraction, X ray diffraction, and magnetic methods. The structurally disordered state of the manganite was achieved under irradiation by fast neutrons (Eeff ≥ 1 MeV) with a fluence of 2 × 1020 cm–2 at a temperature of 340 K. It has been demonstrated that, in the initial sample, the charge ordering of manganese ions of different valences arises at room temperature, which is accompanied by orthorhombic distortions of the cubic spinel structure, and the long-range antiferromagnetic order with the wave vector k = 2π/c(0, 0, 0.44) is observed at low temperatures. It has been established that the structural disordering leads to radical changes in the structural and magnetic states of the LiMn2O4 manganite. The charge ordering is destroyed, and the structure retains the cubic symmetry even at a temperature of 5 K. The antiferromagnetic type of ordering transforms into ferrimagnetic ordering with local spin deviations in the octahedral sublattice due to the appearance of intersublattice exchange interactions

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4.
Инвентарный номер: нет.
   
   G 15


    Galakhov, V. R.
    Electronic structure of defective lithium cobaltites LixCoO2 / V. R. Galakhov, M. Neumann, D. G. Kellerman // Applied Physics A. - 2009. - Vol. 94. - P.497-500 : il. - Bibliogr. : p. 500 (18 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
КОБАЛЬТИТ ЛИТИЯ -- СТРУКТУРА ЭЛЕКТРОННАЯ -- РЕНТГЕНОВСКИЕ ЭМИССИОННЫЕ СПЕКТРЫ
Аннотация: X-ray absorption, resonant X-ray emission, and??X-ray photoelectron spectroscopical methods have been applied for the study of the electronic structure of defective lithium cobaltites LixCoO2 (0.6 . x . 1.0). Resonant O K alfa X-ray emission spectra of LiCoO2 showed localized excitonic??states due to a dd transition between occupied and??unoccupied Co 3d states. On the base of measurements of Co 3s X-ray photoelectron, Co 2p, and O 1s X-ray absorption spectra, it was established that in defective cobaltites??the electronic holes are localized mainly in O 2p states. An evidence of phase separation in LixCoO2 has been found. It was shown that the semiconductor-to-metal transition in LixCoO2 (x <0.76) at about 160 K is not accompanied by??changes in the Co 3d electronic configuration which remains 3d6

\\\\Expert2\\nbo\\Applied Physics A Materials Science and Processing\\2009, v. 94, N 3, p. 497-500.pdf
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5.
Инвентарный номер: нет.
   
   S 89


   
    Structural Disordering in Cr-Doped Li4Ti5O12 Spinels / N. A. Zhuravlev, N. A. Mukhina, D. G. Kellerman, V. S. Gorshkov // Bulletin of the Russian Academy of Sciences: Physics. - 2009. - Vol. 73, № 11. - P. 1522-1524 : il. - Bibliogr. : p. 1524 (8 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ШПИНЕЛИ -- ЛИТИЙ -- ЛЕГИРОВАНИЕ -- ХРОМ
Аннотация: The processes of lithium redistribution in the structure of cubic Li4Ti5O12 spinel, caused by both chromium doping and thermal activation, have been investigated by nuclear magnetic resonance. It is shown that Li ions migrate from tetra to octahedral crystallographic positions with an increase in temperature. This process becomes more pronounced at temperatures above 400 K. In contrast, the fraction of tetrahedrally coordinated Li increases as a result of doping with chromium

\\\\Expert2\\nbo\\Bulletin of the Russian Academy of Sciences Physics\\2009, V. 73, N 11, P.1522-1524.pdf
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6.
Инвентарный номер: нет.
   
   K 31


    Kellerman, D. G.
    Low-Dimensional Exchange Interactions, Structural Deformation, and Antiferromagnetic Ordering in Lithium Manganite LiMnO2 / D. G. Kellerman, N. A. Zhuravlev // Bulletin of the Russian Academy of Sciences: Physics. - 2008. - Vol. 72, № 8. - P. 1155-1158 : il. - Bibliogr. : p. 1159 (9 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
МАНГАНИТ ЛИТИЯ -- СТРУКТУРА КРИСТАЛЛИЧЕСКАЯ -- МАГНИТНЫЕ ПРЕВРАЩЕНИЯ
Аннотация: Structure deformation in lithium manganite LiMnO2 has been analyzed. It is shown that suppression of the Jahn–Teller effect with a decrease in temperature is related to striction effects, which are caused by intercluster exchange interactions. It is concluded that low-dimensional interactions play an important role in the formation of magnetic properties of lithium manganite

\\\\Expert2\\nbo\\Bulletin of the Russian Academy of Sciences Physics\\2008, V. 72, N 8, P.1155-1158.pdf
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7.
Инвентарный номер: нет.
   
   P 36


   
    Peculiarities of antiferromagnetic ordering in orthorhombic LiMnO2 [Текст] / D. G. Kellerman, N. A. Zhuravlev, S. V. Verkhovskii, E. Yu. Medvedev, A. V. Korolev, J. E. Medvedeva // Physics of the Solid State. - 2008. - Vol. 50, № 7. - С. 1294-1302. - Библиогр. : с. 1301 (20 назв.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
АНТИФЕРРОМАГНЕТИКИ -- МАГНИТНАЯ ВОСПРИИМЧИВОСТЬ -- МАНГАНИТ ЛИТИЯ
Аннотация: Data on the antiferromagnetic ordering in orthorhombic lithium manganite LiMnO2 are obtained from magnetic-susceptibility, calorimetry, and nuclear magnetic resonance studies. The minimal hysteresis and the absence of jumps in the temperature dependences of the sublattice magnetization M(T) and the magnetic susceptibility near TN indicate that the ordering occurs through a continuous second-order phase transition. Within the critical temperature range, the M(T–TN) variation is satisfactorily described by a power-law dependence with a critical exponent β= 0.25(4), which is substantially smaller than that predicted for 3D magnetic systems with isotropic Heisenberg exchange. The band structure of orthorhombic LiMnO2 is calculated using the LMTO–ASA method. Taking into account the spin states of manganese ions, an adequate pattern is obtained for the density-of-states distribution with an energy gap near the Fermi level (~0.7 eV), which is in agreement with the measured electrical parameters of lithium manganite. The calculations demonstrate that the exchange interactions between Mn3+ ions leading to antiferromagnetic ordering are significantly anisotropic. It is found that small paramagnetic regions persist in the manganite below the Néel temperature, and it is concluded that the reason for this is partial structural disordering of LiMnO 2 . As a result, a certain fraction of the manganese positions is occupied by lithium ions (Li Mn ) and vise versa (Mn Li ). These defects are not involved in the formation of the ordered magnetic structure and compose a paramagnetic fraction

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8.
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   E 27


   
    Effect of Electronic State of Ions on the Electrochemical Properties of Layered Cathode Materials LiNi1-2xCoxMnxO2 / N. V. Kosova, E. T. Devyatkina, V. V. Kaichev, D. G. Kellerman // Russian Journal of Electrochemistry. - 2008. - Vol. 44, № 5. - P543-549. - Bibliogr. : p. 548-549 (31 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
СЛОИСТЫЕ КАТОДНЫЕ МАТЕРИАЛЫ -- ЛИТИЕВО-ИОННЫЕ БАТАРЕИ -- МАГНИТНАЯ ВОСПРИИМЧИВОСТЬ
Аннотация: The cathode materials of the composition LiNi1– 2xCoxMnxO2(x= 0.1, 0.2. 0.33) synthesized from the Ni, Co, Mn mixed hydroxides and LiOH by using mechanical activation method are studied. It is shown that all synthesized compounds have layered structure described by the space group R-3m. With the decreasing of the nickel content the cell volume and the degree of structure disordering decrease. According to XPS data, the electronic main state of d-ions at the prepared samples' surfaces corresponds to Ni2+,Co3+, and Mn4+. Anincrease in the nickel content leads to the increase of the Ni2p3/2and Co2p3/2binding energy, which points to the change in the Me–O bond covalence. According to magnetic susceptibility measurements data, the nickel ions in LiNi0.6Co0.2Mn2O 2 exist in the two oxidation states: Ni2+and Ni3+. It is shown that this sample has the highest specific discharge capacity (~170 mAh/g). The positions of redox peaks in the differential capacitance curves depend on the sample composition: with the increasing of nickel content they are shifted toward lower voltages

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9.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and SEM/SPM study of disperse materials [Текст] / I. G. Grigorov, I. V. Nikolaenko, D. G. Kellerman, B. A. Gizhevskii, L. V. Zolotukhina, Yu. G. Zainulin // Doklady Physical Chemistry. - 2008. - Vol. 421, № 2. - С. 203-206
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

\\\\Expert2\\nbo\\Doklady Physical Chemistry\\2008, V. 421, N 2, p.203-206.pdf
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10.
Инвентарный номер: нет.
   
   C 91


   
    Crystal structure and magnetic properties of complex oxides Mg4-xNixNb2O9, 0=x=4 [Текст] / N. V. Tarakina, E. A. Nikulina, J. Hadermann, D. G. Kellerman, A. P. Tyutyunnik, I. F. Berger, V. G. Zubkov // Journal of Solid State Chemistry. - 2007. - Vol. 180, № 11. - С. 3180-3187
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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