H 99 Hydration and Proton Transport in Solid Solutions Based on Ba2CaWO6 / I. E. Animitsa, N. A. Kochetova, T. A. Denisova, N. A. Zhuravlev, I. V. Baklanova // Russian Journal of Physical Chemistry A. - 2009. - Vol. 83, № 2. - P197-202 : il. - Bibliogr. : p. 201 (12 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ГИДРАТАЦИЯ -- ПРОТОННЫЙ ПЕРЕНОС -- ТВЕРДЫЕ РАСТВОРЫ -- ВОЛЬФРАМАТЫ ЩЕЛОЧНОЗЕМЕЛЬНЫХ МЕТАЛЛОВ Аннотация: Hydrated alkaline-earth metal tungstates Ba4Ca2 +xW2 –xO12 – 2x with perovskite structure were studied by the thermogravimetry, 1H NMR, IR, and Raman spectroscopy methods. Electrical conductivity and transfer numbers were measured with varying T, Po2, and PH2O. The solid solutions are capable of reversibly intercalating water and can exhibit high-temperature proton transport. The localization of protons on oxygen results in the appearance of energetically nonequivalent OH groups; a small fraction of protons are present in the form of H2O and H3O+ Полный текст |