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1.
Инвентарный номер: нет.
   
   C 47


    Charushin, V. N.
    Fluoroquinolones: Synthesis and Application / V. N. Charushin, E. V. Nosova, G. N. Lipunova // Fluorine in Heterocyclic Chemistry : Издательство "Springer", 2014. - Vol. 2. - С. 111-179. - Bibliogr. : p. 176-179 (377 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
QUINOLONE SYSTEM -- BIOLOGICAL ACTIVITY -- FLUOROQUINOLONES
Аннотация: The data on 6-fluorо-1,4-dihydroquinolin-4-oxo-3-carboxylic acids and their structural analogues accumulated in the literature for the last 10–15 years are reviewed. Synthetic approaches to the quinolone system, as well as all kind of structural modifications by incorporating substituents into 1–8 positions or by means of annelation have been discussed. The “structure-activity” relationships for antibacterial fluoroquinolones, as well as the data on other types of biological activity for the family of bi- and polycyclic fluoroquinolones are presented. The formation of complexes of fluoroquinolones with metals and their applications have been considered. The bibliography

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2.
Инвентарный номер: нет.
   
   L 79


    Lipunova, G. N.
    Fluorinated Quinolines: Synthesis, Properties and Applications / G. N. Lipunova, E. V. Nosova, V. N. Charushin // Fluorine in Heterocyclic Chemistry : Издательство "Springer", 2014. - Vol. 2. - С. 59-109. - Bibliogr. : p. 108-109 (158 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
fLUORINATED QUINOLINES -- SYNTHETIC METHODS -- CYCLOADDITION REACTIONS
Аннотация: The data on the chemistry of fluorinated quinolines available in the literature of the last 10–15 years are presented. A variety of synthetic methods exploiting cyclization and cycloaddition reactions, displacements of halogen atoms or the diaza group, as well as direct fluorinations have been considered. Novel approaches to functionalization of polyfluorinated quinolines, including nucleophilic displacement of fluorine atoms, cross-coupling reactions, and synthesis on the basis of organometallic compounds are discussed. Selected representative examples of fluoroquinolines exhibiting a remarkable biological activity or those quinolines which have already found their applications in medicine will also be discussed in the text. The bibliography

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3.
Инвентарный номер: нет.
   
   R 95


    Rusinov, V. L.
    Fluorinated Triazines / V. L. Rusinov, E. V. Nosova, V. N. Charushin // Fluorine in Heterocyclic Chemistry : Издательство "Springer", 2014. - Vol. 2. - С. 673-716. - Bibliogr. : p. 715-716 (119 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
SYNTHETIC ROUTES -- 1,2,3-TRIAZINES -- 1,2,4-TRIAZINES -- 1,3,5-TRIAZINES
Аннотация: In this chapter data on structure, synthetic routes, reactivity of derivatives of 1,2,3-triazines, 1,2,4-triazines and 1,3,5-triazines − bearing one or several fluorine atoms in heterocyclic ring as well as trifluoromethyl substituted triazines are considered and analyzed, and also their certain representatives are discussed

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4.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis, photochemical and luminescent properties of (E)-2-(2-hydroxyarylethylene)-3-phenylquinazolin-4(3H)-ones [Electronic resource] / I. G. Ovchinnikova, G. A. Kim, E. G. Matochkina, M. I. Kodess, N. V. Barykin, O. S. Eltsov, E. V. Nosova, G. L. Rusinov, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2015. - Vol. 63, № 11. - С. 2467-2477. - Bibliogr. : p. 2477 (22 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
(E)-2-STYRYLQUINAZOLIN-4(3H)-ONES -- LUMINESCENCE -- ORTHO-HYDROXYSTYRYLQUINAZOLINONES
Аннотация: Photoinduced transformations of 2-styrylquinazolinones in solutions were studied using absorption and NMR spectroscopy methods. A possibility of control of the photochemical isomerization rate of quinazolinone 2-(hydroxyaryl)ethenyl derivatives by changing the pH of the medium was demonstrated. The bases and the solvent nature also affect the luminescence intensity of solutions of these compounds in the wavelength range of 550-650 nm. The differences in the steric organization of the ortho-hydroxystyryldiazinone system in crystals and in solutions related to the turn of the aryl group were found. Their influence on the competing processes of luminescence and photochemical transformation of the ethylene fragment were shown. The fact of reversible photo/thermal E-Z-isomerization was established for (E)-2-(2-hydroxystyryl)-3-phenylquinazolin-4(3H)-one.

\\\\expert2\\nbo\\Russian Chemical Bulletin\\2015, 63 (11), 2467-2477.pdf
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5.
Инвентарный номер: нет.
   
   F 70


   
    Fluorine-containing pyrazoles and their condensed derivatives: Synthesis and biological activity [Electronic resource] / G. N. Lipunova, E. V. Nosova, V. N. Charushin, O. N. Chupakhin // Journal of Fluorine Chemistry. - 2015. - Vol. 175. - С. 84-109. - Bibliogr. : p. 108-109 (119 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
HETEROCYCLIC-COMPOUNDS -- NUCLEOPHILES -- IDENTIFICATION
Аннотация: In the frames of this review article the recently obtained data on new synthetic approaches to fluorinated pyrazoles and their condensed analogs, as well as their biological activities have been analyzed.

\\\\expert2\\nbo\\Journal of Fluorine Chemistry\\2015,V.175, p.84-109.pdf
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6.
Инвентарный номер: нет.
   
   B 78


   
    Boron(III) Complexes with N,​N'- and N,​O-​Heterocyclic Ligands: Synthesis and Spectroscopic Properties [Electronic resource] / G. N. Lipunova, E. V. Nosova, V. N. Charushin, O. N. Chupakhin // Comments on Inorganic Chemistry. - 2016. - Vol. 2016. - С. 1153470
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PROPERTIES -- PREPARATION -- SYNTHETIC PREPARATION
Аннотация: This review is focused on consideration of effects of the nature of N,​N'- and N,​O-​bidentate ligands on the structure and optical properties of their B(III) complexes. It has been established that B(III) complexes with asym. N,​N'- and N,​O-​bidentate ligands, such as ortho-​hydroxyphenyl substituted azaheterocycles and heteryl-​β-​ketoimines, exhibit large Stokes shifts, enhanced intensity, and extended range for luminescence in solns. as well as in solid state, comparable with characteristics of the family of BODIPYs derivs. Complexes of some bidentate ligands can be considered as promising fluorophores for applications in biomedical imaging, electroluminescent, solar cell devices, and other fields.

\\\\expert2\\nbo\\Comments on Inorganic Chemistry\\2016. P. 1153470.pdf
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7.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and Photophysical Studies of 2-(Thiophen-2-yl)-4-(morpholin-4-yl) quinazoline Derivatives [Electronic resource] / E. V. Nosova, T. N. Moshkina, G. N. Lipunova, D. S. Kopchuk, P. A. Slepukhin, I. V. Baklanova , V. N. Charushin // European Journal of Organic Chemistry. - 2016. - № 16. - С. 2876-2881
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PHOTOPHYSICS -- CHARGE TRANSFE -- FLUORESCENCE
Аннотация: The synthesis of a series of push-pull aryl and arylethynyl 2-(thiophen-2-yl) quinazoline derivatives is presented. The photophysical properties of the newly generated compounds are also described. Functionalization of the (2-thienyl) quinazoline fluorophore at the 5'-position with aryl and arylethynyl moieties was performed using bromination and subsequent palladium-catalyzed cross-coupling reactions. Optical studies revealed that 4-(diethylamino) phenyl and 4-(diphen-ylamino) phenyl derivatives emit green light upon irradiation, whereas their 4-(9H-carbazol-9-yl) phenyl, methoxyphenyl, thienyl and arylethynyl counterparts are characterized by blue light emission capabilities. The effect of protonation has also been studied, and the ability of some of these molecules to function as colorimetric and luminescent pH sensors has been demonstrated with significant color changes and luminescence switching upon the introduction of acid.

\\\\expert2\\NBO\\European Journal of Organic Chemistry\\2016, №16. p.2876-2881.pdf
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8.
Инвентарный номер: нет.
   
   N 85


    Nosova, E. V.
    New benzazine ligands and their complexes: synthesis and photophysical properties / E. V. Nosova, G. N. Lipunova, V. N. Charushin // International Congress on Heterocyclic Chemistry «KOST-2015», Moscow, October 18-23 2015 : book of abstr. - Moscow, 2015. - С. 120
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BENZAZINE LIGANDS -- PHOTOPHYSICAL PROPERTIES -- LIGANDS BENZAZINE

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9.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis, structure and photoluminescent properties of BF2 and BPh2 complexes with N,O-benzazine ligands [Electronic resource] / E. V. Nosova, T. N. Moshkina, G. N. Lipunova, I. V. Baklanova , P. A. Slepukhin, V. N. Charushin // Journal of Fluorine Chemistry. - 2015. - Vol. 175. - С. 145-151. - Bibliogr. : p. 150-151 (29 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
N,O-BIDENTATE LIGANDS -- BPh2 COMPLEXES -- BF2 COMPLEXES
Аннотация: Novel N,O-bidentate BF2 and BPh2 complexes have been prepared in good to excellent yields through coordination of 8-hydroxy-2-methylquinolines and 2-(2-hydroxyphenyl)-3H-quinazolin-4-ones with boron trifluoride etherate or triphenylborane under mild conditions. All complexes have been characterized by H-1, B-11 and F-19 NMR, mass-spectrometry and X-ray crystallography data. Some complexes have been found to exhibit a significant fluore.scence in acetonitrile solutions. Electronic and site effects of substituents in both heterocyclic and phenol fragments proved to have a profound impact on quantum yields.

\\\\expert2\\nbo\\Journal of Fluorine Chemistry\\2015,V.175, p.145-151.pdf
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10.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis, crystal structures, and fluorescent properties of zinc(II) complexes with benzazino-2-carboxalidin-2-aminophenols [Electronic resource] / E. V. Nosova, T. V. Stupina, O. N. Chupakhin, M. S. Valova, P. A. Slepukhin, V. N. Charushin // Open Chemistry. - 2015. - Vol. 13, № 1. - С. 61-67. - Bibliogr. : p. 67 (26 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BENZAZINE-2-CARBALDEHYDE -- O-AMINOPHENOL -- SCHIFF BASE
Аннотация: Complexes ZnL2 with novel fluorinated benzazines as tridentate ligands (HL = 6,7-difluoroquinoxalinand 6,7-difluoroquinolincarboxalidin-2-aminophenol) have been prepared. The photophisical properties of the ligands and the complexes has been studied.

\\\\expert2\\nbo\\Open Chemistry\\2015. V. 13(1). P. 61-67.pdf
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