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1.

Вид документа :
Шифр издания : 54/C 31
Автор(ы) : Titova Yu. A., Fedorova O. V., Ovchinnikova I. G., Rusinov G. L., Charushin V. N.
Заглавие : Catalytic effect of nanosized metal oxides on the knoevenagel reaction
Место публикации : Russian Journal of Applied Chemistry. - 2012. - Vol.85, №4. - С. 656-660
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): catalytic effect --metal oxides --knoevenagel reaction
Аннотация: The effect of nanosized metal oxides (Al, Mg, Cu, Ni oxides) on the synthesis of chalcones that are key intermediate in the synthesis of Nitrendipine and Felodipine drugs was examined
\\\\Expert2\\nbo\\Russian Journal of Applied Chemistry\\2012, v. 85, N 4, p.656.pdf
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2.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Zhilina E. F., Slepukhin P. A., Boltacheva N. S., Pervova M. G., Chizhov D. L., Filyakova V. I., Charushin V. N.
Заглавие : Synthesis, structure and complexation of the fluorinated 1,3-enaminoketones containing at the nitrogen atom substituents with a terminal C≡C bond
Место публикации : Russian Journal of General Chemistry. - 2012. - Vol. 82, №12. - С. 1962-1969
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): synthesis--nitrogen--terminal c≡c bonds
Аннотация: The reaction of fluorinated lithium 1,3-diketonates with propargylamine hydrochloride and 1,1,1-trifluorpentane-2,4-dione or 1,1,1-trifluoro-4-methoxypent-3-en-2-one with propargylamine and 3-aminophenylacetylene were performed to obtain fluorinated 1,3-enaminones containing at a nitrogen atom substituents with terminal C≡C bonds: (Z)-1,1,1-trifluoro-4-(2-propynylamino)-3-pentene-2-one, (Z)-1,1,2,2-tetrafluoro-5-(2-propynylamino)-4-hexen-3-one, and 4-(3-ethynylphenylamino)-1,1,1-trifluoropentyl-3-en-2-one. Reactions of 4-(3-ethynyl-phenylamino)-1,1,1-trifluoro-pentyl-3-en-2-one with Cu(II) acetate or nanosized powder of copper or its oxides led to the respective chelate complex. The structure of (Z)-1,1,2,2-tetrafluoro-5-(2-propynylamino)-4-hexen-3-one and a copper complex of 4-(3-etinilphenylamino)-1,1,1-trifluoropenta-3-en-2-one was determined by XRD
\\\\Expert2\\NBO\\Russian Journal of General Chemistry\\2012, V. 82, N 12, p. 1962–1969.pdf
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3.

Вид документа : Статья из журнала
Шифр издания : 54/T 86
Автор(ы) : Chizhov D. L., Pervova M. G., Samorukova M. A., Khmara E. F., Filyakova V. I., Saloutin V. I., Charushin V. N.
Заглавие : Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N?-1,2-phenylen-bis(beta-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes
Место публикации : Journal of Fluorine Chemistry. - 2011. - Vol. 132, № 6. - С. 394-401
Примечания : Bibliogr. : p. 401 (19 ref.)
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: An effecient synthetic method for fluorinated tridentate ?-aminoenones and tetradentate bis(?-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(?-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described
\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2011, v. 132, p.394.pdf
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4.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Young Rang Uhm , Hi Min Lee , Fedorova O. V., Ovchinnikova I. G., Valova M. S., Rusinov G. L., Charushin V. N., Chang Kyu Rhee
Заглавие : Synthesis of carbon encapsulated metal (Ni and Cu) nano particles and applications for chiral catalysts
Место публикации : Research on Chemical Intermediates . - 2010. - Vol. 36, № 6-7. - С. 867-873
Примечания : Bibliogr. : p. 873 (15 ref.)
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Carbon-encapsulated Ni and Cu nanoparticles with a core/shell structure were synthesized by levitational gas condensation (LGC). Methane (CH4) gas was used to coat the surface of the Ni and Cu nanoparticles. The Ni particles had a core diameter of 10 nm, and were covered by 2–3 nm thin carbon layers. In the case of Cu, the particles had a core diameter of 30 nm, and multi-shells with a thickness of 2–3 nm. Biginelli reaction in the presence of l-proline and Ni encapsulated nanoparticles was carried out to change the ratio between stereoisomers in favor of the S-enantiomer for 3,4–dihydropyrimidine (DHPM) with an excess of about 18%
\\\\Cserver\\dist\\НБО\\Электронная библиотека_Библиогр1\\Research on Chemical Intermediates\\2010, v. 36, N. 6-7, p.867.pdf
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5.

Вид документа : Статья из журнала
Шифр издания : 54/N 50
Автор(ы) : Zhilina E. F., Chizhov D. L., Sidorov A. A., Aleksandrov G. G., Kiskin M., Slepukhin P. A., Fedin M., Charushin V. N.
Заглавие : Neutral tetranuclear Cu(II) complex of 2,6-di(5-trifluoromethylpyrazol-3-yl)pyridine: Synthesis, characterization and its transformation with selected aza-ligands
Место публикации : Polyhedron. - 2013. - Vol.53. - С. 122-131
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): copper (ii) complex--x-ray--magnetic properties
Аннотация: New tetranuclear Cu(II) complex [Cu4(L)4]·MeCN (1) with 2,6-di(5-trifluoromethyl-1H-pyrazol-3-yl)pyridine (H2L) was synthesized. It has been shown that treatment of 1 with selected aza-ligands (pyridine, 2,2′- and 4,4′-bipyridyl, 2,3,5,6-tetra-(pyridine-2-yl)pyrazine, 2,2′;6′,2″-terpyridine and 1,4-diazabicyclo[2.2.2]octane) leads to formation of other Cu(II) complexes with different nuclearity: [Cu(L)py2] (2), [Cu(L)(2,2′-bpy)] (3), [Cu(L)2(tppz)]·THF (5), [Cu(L)tpy]·C6H5CN (4), {[Cu2(L)2(4,4′-bpy)2]·(C6H5CH3)·MeCN}n (6) and {[Cu(L)DABCO]·2MeCN}n (7). Obtained compounds were characterized by IR spectroscopy, X-ray crystallography data, EPR and SQUID magnetic measurements. --------------------------------------------------------------------------------
\\\\Expert2\\NBO\\Polyhedron\\2013. v.53. p.122.pdf
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6.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Cherprakova E. M., Verbitskiy E. V., Kiskin M. A., Aleksandrov G. G., Slepukhin P. A., Sidorov A. A., Starichenko D.V., Shvachko Yu.N., Eremenko I. L., Rusinov G. L., Charushin V. N.
Заглавие : Synthesis and characterization of new complexes derived from 4-thienyl substituted pyrimidines [Электронный ресурс]
Место публикации : Polyhedron. - 2015. - Vol. 100. - С. 89-99
Систем. требования: http://apps.webofknowledge.com/
Примечания : Bibliogr. : p. 98-99 (42 ref.). - 18.01.16
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): pyrimidine--cyclopalladation --magnetic-properties
Аннотация: The behavior of 4-thienyl substituted pyrimidine ligands (L1-3) has been studied for the series of their reactions with various salts of 3d metals (Co, Zn, Ni, Cu) and platinoids (Pt, Pd). In particular, mononuclear Co(OTf)(2)(L1-3)(2)(H2O)(2)(MeCN)(2) (1), binuclear Co-2(Piv)(2)(L1-3)(4) (2a,b), Cu-2(Piv)(2)(L1-3)(2) (5a,b), heterometallic polynuclear Li2Co2(Piv)(6)(L1-3)(2) (4) and chelate [(L-1)Pd(OAc)](2) (6) complexes have been obtained. The structures of all complexes have been established by X-ray diffraction. Also magnetic properties of coordination compounds 1, 2, 4 and 5 have been studied in details. In particular, mononuclear Co(II) complexes I and 4 proved to exhibit paramagnetism with large positive zero-field splitting parameters. Dinuclear Co(II) complexes 2a,b show weak antiferromagnetic interactions. Dinuclear Cu(II) complexes 5a,b demonstrate strong antiferromagnetic superexchange interactions via four carboxylate bridges. The systems 2a,b and 5a,b are isolated as exchange coupled dimers
\\\\expert2\\nbo\\Polyhedron\\2015, v.100, p.89-99.pdf
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mohammed M. S. I., Kovalev I. S., Slovesnova N. V., Sadieva L. K., Platonov V. A., Novikov A. S., Santra S., Morozova J. E., Zyryanov G. V., Charushin V. N., Ranu B. C.
Заглавие : Polyaromatic hydrocarbon (PAH)-based aza-POPOPS: synthesis, photophysical studies, and nitroanalyte sensing abilities
Место публикации : International journal of molecular sciences. - 2023. - Vol. 24, № 12. - С. 10084
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): aza-popops--click reactions--chemosensors
Аннотация: 1,4-Bis(5-phenyl-2-oxazolyl)benzene (POPOP) is a common scintillation fluorescent laser dye. In this manuscript, the synthesis of 2-Ar-5-(4-(4-Ar'-1H-1,2,3-triazol-1-yl)phenyl)-1,3,4-oxadiazoles (Ar, Ar' = Ph, naphtalenyl-2, pyrenyl-1, triphenilenyl-2), as PAH-based aza-analogues of POPOP, by means of Cu-catalyzed click reaction between 2-(4-azidophenyl)-5-Ar-1,3,4-oxadiazole and terminal ethynyl-substituted PAHs is reported. An investigation of the photophysical properties of the obtained products was carried out, and their sensory response to nitroanalytes was evaluated. In the case of pyrenyl-1-substituted aza-POPOP, dramatic fluorescence quenching by nitroanalytes was observed.
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8.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Tolshchina S. G., Ishmetova R. I., Ignatenko A. V., Korotina A. V., Slepukhin P. A., Charushin V. N.
Заглавие : Synthesis and transformations of cyanomethyl-1,2,4,5-tetrazines
Место публикации : Chemistry of Heterocyclic Compounds. - 2013. - Vol.49, №4. - С. 604-617
Примечания : Библиогр.: с. 617 (18 ref.)
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): s-tetrazine --malonodinitrile--nucleophilic substitution
Аннотация: Derivatives of s-tetrazine containing malonodinitrile, ethyl cyanoacetate, and 1,3-indanedione fragments were synthesized by the nucleophilic substitution of heterocyclic groups in 3,6-diazolyl-1,2,4,5-tetrazines. Coordination compounds of the cyanomethyltetrazine anion with Cu+, Mn2+, and the tetrathiafulvalene radical cation were obtained, and their structures were determined. A transformation of cyanomethyltetrazines to pyrrolo[1,2-b][1, 2, 4, 5]tetrazines catalyzed by metal cations was discovered
\\\\expert2\\NBO\\Chemistry of Heterocyclic Compounds\\2013, v.49, N 4, p. 604-617.pdf
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9.

Вид документа : Статья из журнала
Шифр издания : 54/H 62
Автор(ы) : Galliamova L. A., Varaksin M. V., Chupakhin O. N., Slepukhin P. A., Charushin V. N.
Заглавие : Heterocyclic and Open-Chain Carboranes via Transition-Metal-Free C-H Functionalization of Mono- and Diazine-N-oxides [Электронный ресурс]
Место публикации : Organometallics. - 2015. - Vol. 34, № 21. - С. 5285-5290
Систем. требования: http://apps.webofknowledge.com/
Примечания : Bibliogr. : p. 5290 (27 ref.). - 18.01.16
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): cyclometalated iridium complexes--neutron-capture therapy--pharmacophores
Аннотация: For the first time, the direct C(sp(2))-H functionalization methodology has successfully been applied to cause nucleophilic modification of mono- and diazine-N-oxides with the 1,2-closo-carborane moiety. As a result of these cross-coupling reactions uncatalyzed by transition metals, a series of novel C-modified heterocyclic and open-chain (vinyl acetylene) carboranes have been obtained. Complexes of phenanthrolinyl-substituted omicron-carborane with Cu(II) of various architectures have been synthesized.
\\\\expert2\\nbo\\Organometallics\\2015. V. 34, N 21. P. 5285.pdf
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10.

Вид документа : Статья из журнала
Шифр издания : 54/H 62
Автор(ы) : Ovcharenko V., Fokin S.V., Romanenko G. V., Bogomyakov A. S., Yachevskii D. S., Chizhov D. L., Charushin V. N., Chupakhin O. N.
Заглавие : Heterospin complexes of fluorinated dinuclear Cu(II) and Mn(II) triketonates with nitroxides [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2010. - Vol. 59, № 6. - С. 1162-1174: il.
Систем. требования: http://www.springerlink.com/content/d0v1616044t268u0/fulltext.pdf
Примечания : Bibliogr. : p. 1174 (21 ref.). - 28.10.2011 г.
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Dinuclear heterospin complexes of CuII and MnII 1,1,1,7,7,7-hexafluoroheptane-2,4,6-trionates ([Cu2L2] and [Mn2L2], respectively) with nitronyl nitroxides 2-R-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide 1-oxyls (NIT-R, R = H, Me, Et, m-C5H4N, m-NCC6H4, p-NCC6H4, PzMe) and the diradical NIT-Pz-(CH2)4-Pz-NIT (Pz is 1,4-pyrazolylene) were synthesized and structurally characterized. In the complexes under study, the CuII atom tends to have the square-pyramidal coordination environment, and the MnII atom is in an octahedral environment. The magnetochemical investigation of the compounds in the temperature range of 2–300 K showed that the antiferromagnetic exchange coupling dominates in the [Cu2L2] molecules, whereas this coupling in [Mn2L2] is manifested in the experimental plot µeff(T) at T 100 K. The magnetic properties of the heterospin complexes of [Cu2L2] with NIT-R are also determined by the intramatrix antiferromagnetic exchange coupling. For the complexes of [Mn2L2] with NIT-R, the coordination mode of the nitroxide plays a decisive role.
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2010, 59 (6), 1162-1174.pdf
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